Franck–Condon effects in resonance Raman spectra and excitation profiles

1979 ◽  
Vol 71 (9) ◽  
pp. 3561-3569 ◽  
Author(s):  
Willem Siebrand ◽  
Marek Z. Zgierski
1999 ◽  
Vol 19 (1-4) ◽  
pp. 191-194
Author(s):  
Fabrizia Negri ◽  
Giorgio Orlandi

The vibrational structure of the T1 resonance Raman spectra of β-ionylidene acetaldehyde (C15 aldehyde) and retinal are analyzed with the help of semiempirical quantum chemical calculations. The T1 equilibrium structures and vibrational force fields, along with the structure in the Tn state which is in resonance with the exciting wavelength, are obtained and employed to model the spectra under the assumption of a dominant Franck–Condon mechanism.


2009 ◽  
pp. n/a-n/a ◽  
Author(s):  
Robert Hanf ◽  
Stefanie Tschierlei ◽  
Benjamin Dietzek ◽  
Sonja Seidel ◽  
Gudrun Hermann ◽  
...  

1983 ◽  
Vol 213 (2) ◽  
pp. 503-506 ◽  
Author(s):  
G Musci ◽  
A Desideri ◽  
L Morpurgo ◽  
A Garnier-Suillerot ◽  
L Tosi

Resonance-Raman spectra of Japanese-lacquer-tree (Rhus vernicifera) laccase, type-2-copper-depleted laccase and the latter form treated with H2O2 were measured in liquid and frozen solution, on excitation into the 600 nm absorption band. Significant changes in intensity and/or frequency of the bands lying in the 370-430 cm-1 region were observed on freezing, indicating local structural rearrangements taking place at the blue copper site. These findings corroborate previous suggestions based on e.p.r. measurements and redox data [Morpurgo, Calabrese, Desideri & Rotilio (1981) Biochem. J. 193, 639-642]. They show the strong dependence of the physical properties of blue copper centres on local symmetry. Some conclusions on the origin of the Raman bands are also drawn.


2010 ◽  
Vol 83 (10) ◽  
pp. 1162-1169
Author(s):  
Tomoko Miyazaki ◽  
Chizu Shimokawa ◽  
Toshio Matsushita ◽  
Shinobu Itoh ◽  
Junji Teraoka

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