Dynamics of collisional relaxation of vibrational energy distributions in a thermal unimolecular system. Surface collisions

1979 ◽  
Vol 71 (1) ◽  
pp. 538-539 ◽  
Author(s):  
D. F. Kelley ◽  
B. D. Barton ◽  
L. Zalotai ◽  
B. S. Rabinovitch
Keyword(s):  
Vibrational Energy ◽  
Collisional Relaxation ◽  
Energy Distributions

Wavelength-dependent photodissociation as a probe for vibrational energy distributions in molecular ions

1996 ◽  
Vol 29 (13) ◽  
pp. 2763-2773 ◽  
Author(s):  
J J Blangé ◽  
X Urbain ◽  
H Rudolph ◽  
H A Dijkerman ◽  
H C W Beijerinck ◽  
...  
Keyword(s):  
Vibrational Energy ◽  
Molecular Ions ◽  
Energy Distributions

Vibrational Energy Transfer in Carbon Monoxide

1972 ◽  
Vol 50 (9) ◽  
pp. 889-897 ◽  
Author(s):  
P. H. Dawson ◽  
W. G. Tam
Keyword(s):  
Energy Exchange ◽  
Vibrational Energy ◽  
Transverse Flow ◽  
Vibration Energy ◽  
Excess Oxygen ◽  
Experimental Measurements ◽  
Energy Distributions ◽  
Vibrationally Excited ◽  
Population Distributions

The role of V–V processes in vibrationally excited CO systems in the longitudinal and transverse flow chemical lasers is studied. Initial vibrational energy distributions of CO formed by the O + CS reaction are deduced from chemiluminescent data using calculated values of the vibration energy exchange probabilities. The time evolution of the population distributions is then obtained by computer simulation. The results are compared with experimental measurements. The effects of excess oxygen and of "cold" CO on the population distributions are also discussed.

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