Production and relaxation cross sections for the shear viscosity Senftleben–Beenakker effect. I. Formal expressions and their coupled‐states and infinite‐order–sudden approximations for atom–diatom systems

1979 ◽  
Vol 71 (1) ◽  
pp. 415-425 ◽  
Author(s):  
W.‐K. Liu ◽  
F. R. McCourt ◽  
D. E. Fitz ◽  
Donald J. Kouri
1987 ◽  
Vol 60 (2) ◽  
pp. 337-360 ◽  
Author(s):  
James L. White ◽  
Yeh Wang ◽  
Avraam I. Isayev ◽  
Nobuyuki Nakajima ◽  
Frederick C. Weissert ◽  
...  

Abstract This paper marks a first effort to develop a fundamental basis for die flow analysis and design for rubber compounds. We have accomplished a modelling of the shear viscosity function and its application to one- and two-dimensional shearing in die cross sections. There are major limitations in what we have done, much of which is apparent even in the early work of Mooney. In particular, we have not considered (i) slip phenomena on die walls, (ii) die entrance and exit pressure losses associated with converging and diverging dies, nor (iii) extrudate swell. We have an active research in our laboratories investigating these problems. In the future, we are seeking to generalize the procedures described in this paper to more complex die designs. Inclusion of entrance and exit effects and rigorous analysis of coathanger dies requires the handling of elongational flow contributions, a still unsolved problem.


1997 ◽  
Vol 52 (10) ◽  
pp. 695-701
Author(s):  
Markus Hammer ◽  
Wolfhart Seidel

Abstract Rotationally unresolved differential cross sections were measured in crossed molecular beam experiments by scattering Helium atoms from Ethane, 1,1-Difluoroethane, 1,1,1,2-Tetrafluoroethane and Hexafluoroethane. The damping of observed diffraction oscillations was used to extract anisotropic interaction potentials for these scattering systems applying the infinite order sudden approximation (IOSA). Binary macroscopic parameters such as second heterogeneous virial coefficients and the coefficients of diffusion and viscosity were computed from these potentials and compared to results from macroscopic experiments.


1982 ◽  
Vol 76 (10) ◽  
pp. 5112-5127 ◽  
Author(s):  
W.‐K. Liu ◽  
F. R. McCourt ◽  
D. E. Fitz ◽  
D. J. Kouri

1981 ◽  
Vol 75 (3) ◽  
pp. 1496-1508 ◽  
Author(s):  
W.‐K. Liu ◽  
F. R. McCourt ◽  
D. E. Fitz ◽  
D. J. Kouri

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