The coordination (hydration) of rare earth ions in aqueous chloride solutions from x‐ray diffraction. II. LaCl3, PrCl3, and NdCl3a)

1979 ◽  
Vol 70 (8) ◽  
pp. 3758-3763 ◽  
Author(s):  
Anton Habenschuss ◽  
Frank H. Spedding
Keyword(s):  
Rare Earth ◽  
Rare Earth Ions ◽  
X Ray Diffraction ◽  
Chloride Solutions ◽  
X Ray ◽  
Aqueous Chloride

Synthesis, Morphology Control and Luminescent Properties of Rare Earth Ion-Doped CaWO4 Microstructures

2016 ◽  
Vol 16 (4) ◽  
pp. 4029-4034 ◽  
Author(s):  
Chunxia Liu ◽  
Lixia Yang ◽  
Dan Yue ◽  
Mengnan Wang ◽  
Lin Jin ◽  
...  
Keyword(s):  
Rare Earth ◽  
Uv Light ◽  
Luminescent Properties ◽  
Average Diameter ◽  
Rare Earth Ions ◽  
X Ray Diffraction ◽  
Hydrothermal Route ◽  
Rare Earth Ion ◽  
X Ray ◽  
Facile Hydrothermal Route

Rare earth ions (Tb3+, Eu3+) doped CaWO4 microstructures were synthesized by a facile hydrothermal route without using any templates and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence (PL) spectrum. The results indicate that the asprepared samples are well crystallized with scheelite structure of CaWO4, and the average diameter of the microstructures is 2∼4 μm. The morphology of CaWO4:Eu3+ microstructures can be controllably changed from microspheres to microflowers through altering the doping concentration of Eu3+ from 3% to 35%, and the microflowers are constructed by a number of CaWO4:Eu3+ nanoflakes. Under the excitation of UV light, the emission spectrum of CaWO4:Eu3+ is composed of the characteristics emission of Eu3+ 5D0-7FJ (J = 1, 2, 3, 4) transitions, and that of CaWO4:Tb3+ is composed of Tb3+ 5D4-7FJ (J = 6, 5, 4, 3) transitions. Both of the optimal doping concentrations of Tb3+ and Eu3+ in CaWO4 microstructures are about 5%.

Effects of Acidity on Nitrogen-Heterocyclic Compounds with Rare Earth Coordination and the Structure of Protonated Phenanthroline

2011 ◽  
Vol 233-235 ◽  
pp. 2808-2811
Author(s):  
Huan Huan Li ◽  
Hai Bin Chu ◽  
Ying Nan Chen ◽  
Xiao Tao Fu ◽  
Hui Juan Sun ◽  
...  
Keyword(s):  
Rare Earth ◽  
Heterocyclic Compounds ◽  
Crystal Structure Analysis ◽  
Rare Earth Ions ◽  
Molecular Formula ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
X Ray ◽  
Rare Earth Coordination ◽  
Single Crystal Structure Analysis

2,3-bis(2-pyridyl)-5,6-dihydropyrazine and a protonated phenanthroline (Phen) have been synthesized and the structure of protonated Phen is established by X-ray diffraction single crystal structure analysis. The coordination reactions of Phen, 2,2'- bipyridine and 2,3-bis(2-pyridyl)-5,6-dihydropyrazine with rare earth ions in low pH have been studied. The results show that 2,3-bis(2-pyridyl)-5,6-dihydropyrazine is hydrolyzed to be 2,2’-pyridil and protonated ethylenediamine. Meanwhile, Phen combines with proton, which results that nitrogen atoms can not coordinate with rare earth ions. The molecular formula of protonated Phen is C12H8N2HCl·H2O. It crystallizes in the triclinic space group P -1 (2), with a = 7.1212(14) Å, b = 7.2786(15) Å, c = 20.817(4) Å, α = 90.00º, β = 96.69(3) º, γ = 90.00 º, V = 1071.65(379) Å3, Z = 4.

scholarly journals Single-Crystal Growth of Metallic Rare-Earth Tetraborides by the Floating-Zone Technique

Crystals ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 211 ◽  
Author(s):  
Daniel Brunt ◽  
Monica Ciomaga Hatnean ◽  
Oleg A. Petrenko ◽  
Martin R. Lees ◽  
Geetha Balakrishnan
Keyword(s):  
Rare Earth ◽  
Single Crystal Growth ◽  
Rare Earth Ions ◽  
Floating Zone ◽  
X Ray Diffraction ◽  
Zone Method ◽  
X Ray ◽  
Resistivity Measurements ◽  
Field Dependent ◽  
The Rare Earth

The rare-earth tetraborides are exceptional in that the rare-earth ions are topologically equivalent to the frustrated Shastry-Sutherland lattice. In this paper, we report the growth of large single crystals of RB 4 (where R = Nd, Gd → Tm, and Y) by the floating-zone method, using a high-power xenon arc-lamp furnace. The crystal boules have been characterized and tested for their quality using X-ray diffraction techniques and temperature- and field-dependent magnetization and AC resistivity measurements.

Magnetic properties of (Sr1.85Ln0.15)FeMoO6 with Ln = Sr, La, Ce, Pr, Nd, Sm and Eu

2011 ◽  
Vol 239-242 ◽  
pp. 3109-3112 ◽  
Author(s):  
Qin Zhang ◽  
Qing Wang ◽  
Zhen Cui Sun ◽  
Ke Yan Wang
Keyword(s):  
Magnetic Properties ◽  
Rare Earth ◽  
Ionic Radius ◽  
Single Phase ◽  
Magnetic Measurements ◽  
Rare Earth Ions ◽  
X Ray Diffraction ◽  
X Ray ◽  
Rare Earth Doped ◽  
The Eu

Rare-earth-doped compounds (Sr1.85Ln0.15)FeMoO6(Ln=Sr, La, Ce, Pr, Nd, Sm and Eu) have been prepared by solid-state reaction. Crystal structure and magnetic properties were investigated by means of X-ray diffraction and magnetic measurements. All the samples are single phase and belong to the I4/m space group. Due to the competing contributions of electron doping and steric effects, the unit-cell volume of the doped compounds changes slightly and does not vary systematically with the ionic radius of the rare-earth ions. The temperature dependence of the magnetization of (Sr1.85Ln0.15)FeMoO6indicates that the Curie temperature of the doped compounds has increased upon doping, except for the Eu-doped compound.

Structure of ultraphosphate glasses with small rare-earth ions by X-ray diffraction

2011 ◽  
Vol 357 (14) ◽  
pp. 2516-2521 ◽  
Author(s):  
U. Hoppe ◽  
N.P. Wyckoff ◽  
R.K. Brow ◽  
U. Rütt
Keyword(s):  
Rare Earth ◽  
Rare Earth Ions ◽  
X Ray Diffraction ◽  
X Ray

Synthesis and Structures of Rare Earth 3-(4′-Methylbenzoyl)-propanoate Complexes – New Corrosion Inhibitors

2017 ◽  
Vol 70 (5) ◽  
pp. 478 ◽  
Author(s):  
Caspar N. de Bruin-Dickason ◽  
Glen. B. Deacon ◽  
Craig M. Forsyth ◽  
Schirin Hanf ◽  
Oliver B. Heilmann ◽  
...  
Keyword(s):  
Rare Earth ◽  
Corrosion Inhibitors ◽  
Free Acid ◽  
Rare Earth Ions ◽  
X Ray Diffraction ◽  
Bulk Materials ◽  
X Ray ◽  
Rare Earth Chloride ◽  
Diffraction Patterns ◽  
Paramagnetic Shifts

A series of rare earth 3-(4′-methylbenzoyl)propanoate (mbp–) complexes [RE(mbp)3(H2O)] (RE = rare earth = Y, La, Ce, Nd, Ho, Er) have been prepared by either metathesis reactions between the corresponding rare earth chloride and Na(mbp) or protolysis of rare earth acetates by the free acid. Single-crystal X-ray diffraction studies of [RE(mbp)3(H2O)] (RE = Ce, Nd) and [Ce(mbp)3(dmso)] reveal a 1D carboxylate-bridged polymeric structure in the solid state, featuring 9-coordinate rare earth ions. X-ray powder diffraction patterns of the bulk materials indicates that all of the [RE(mbp)3(H2O)] complexes except RE = La are isomorphous. Hence, there is no structural change from the complex with RE = Ce to that with RE = Er despite the lanthanoid contraction. The 1H NMR spectra of the RE = Ho or Er complexes in (CD3)2SO show large paramagnetic shifts and broadening of the CH2 resonances, indicating the retention of substantial carboxylate coordination in solution.

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