Photoelectron spectroscopy using a supersonic molecular beam source. The 2B3u+e−←1Ag transition in ethylene

1979 ◽  
Vol 70 (10) ◽  
pp. 4574-4580 ◽  
Author(s):  
P. M. Dehmer ◽  
J. L. Dehmer
Vacuum ◽  
1980 ◽  
Vol 30 (3) ◽  
pp. 121-124 ◽  
Author(s):  
E D'Anna ◽  
G Leggieri ◽  
G Conforti ◽  
F Del Giallo ◽  
F Pieralli ◽  
...  

2004 ◽  
Vol 82 (6) ◽  
pp. 779-790 ◽  
Author(s):  
T C Steimle ◽  
Jamie Gengler ◽  
Jinhai Chen

The high-resolution laser-induced fluorescence spectrum of a molecular beam sample of calcium monohydride (CaH) in the region of the strongly overlapped (1,0) A2Π – X2Σ+ and (0,0) B2Σ+ –  X2Σ+ band systems near 630 nm and the (0,0) A2Π –  X2Σ+ band system near 690 nm have been recorded and analyzed. The spectral features exhibit a small splitting that is attributed to proton magnetic hyperfine interaction in the X2Σ+ (v = 0) state. The energy levels of the A2Π(v = 0) vibronic state were modeled using a traditional "effective" Hamiltonian approach, whereas those for the interacting A2Π(v = 1)/B2Σ+(v = 0) vibronic levels were modeled by augmenting the traditional effective Hamiltonian with terms to account for local perturbations. An interpretation of the field-free parameters is presented.Key words: calcium monohydride, molecular beam, fluorescence.


1991 ◽  
Vol 62 (9) ◽  
pp. 2154-2158 ◽  
Author(s):  
Hidehiko Nonaka ◽  
Takashi Shimizu ◽  
Kazuo Arai

1992 ◽  
Vol 63 (8) ◽  
pp. 3939-3943 ◽  
Author(s):  
D. J. Auerbach ◽  
C. T. Rettner

2002 ◽  
Vol 09 (02) ◽  
pp. 797-801 ◽  
Author(s):  
R. DENECKE ◽  
M. KINNE ◽  
C. M. WHELAN ◽  
H.-P. STEINRÜCK

In this contribution we introduce a new apparatus combining high-resolution photoelectron spectroscopy and supersonic molecular beam techniques designed to follow simple surface reactions like adsorption, desorption or oxidation in situ in a time- and temperature-resolved manner. Using high brightness synchrotron radiation high resolution core-level spectra can be obtained in less than 3 s. The molecular beam allows for local pressures of up to 1 · 10-5 mbar and translational energies of the molecules of up to 2 eV in the case of CO. Preliminary examples of CO adsorption on Pt(111) are shown, where kinetic parameters can be derived from the coverage dependence of the different adsorption sites.


2013 ◽  
Vol 84 (9) ◽  
pp. 093303 ◽  
Author(s):  
S. D. Eder ◽  
B. Samelin ◽  
G. Bracco ◽  
K. Ansperger ◽  
B. Holst

2008 ◽  
Vol 95 (1) ◽  
pp. 29-35 ◽  
Author(s):  
Alexios Papadimitratos ◽  
Aram Amassian ◽  
Aravind S. Killampalli ◽  
Jared L. Mack ◽  
George G. Malliaras ◽  
...  

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