Resonance Raman spectra of copper tetraphenylporphyrin: Effects of strong vibronic coupling on excitation profiles and the absorption spectrum

1978 ◽  
Vol 69 (12) ◽  
pp. 5361-5374 ◽  
Author(s):  
J. A. Shelnutt ◽  
D. C. O’Shea
1999 ◽  
Vol 19 (1-4) ◽  
pp. 71-74 ◽  
Author(s):  
Xuming Zheng ◽  
David Lee Phillips

We have obtained A-band absorption resonance Raman spectra of 1-chloro-2- iodoethane in cyclohexane solution. We have done preliminary time-dependent wavepacket calculations to simulate the resonance Raman intensities and absorption spectrum in order to learn more about the short-time photodissociation dynamics. We compare our preliminary results for 1-chloro-2-iodoethane with previous resonance Raman results for iodoethane and find that there appears to be more motion along non- C—I stretch modes for 1-chloro-2-iodoethane than for iodoethane. This is consistent with results of TOF photofragment spectroscopy experiments which indicate much more internal excitation of the photoproducts from 1-chloro-2-iodoethane photodissociation than the photoproducts from iodoethane photodissociation.


1990 ◽  
Vol 140 (2) ◽  
pp. 317-329 ◽  
Author(s):  
T.A. Mattioli ◽  
L.V. Haley ◽  
J.A. Koningstein

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