Mechanisms of central O‐atom abstraction reactions: A molecular beam, laser‐induced fluorescence study of Group IIIB + ROH systems

1978 ◽  
Vol 68 (4) ◽  
pp. 1794-1802 ◽  
Author(s):  
K. Liu ◽  
J. M. Parson
1988 ◽  
Vol 66 (8) ◽  
pp. 1936-1941 ◽  
Author(s):  
Guo-Zhong He ◽  
Jue Wang ◽  
R. S. Tse ◽  
Nan-Quan Lou

Energy partitioning of the CaI product from the Ca + CH3I [1] and Ca + CF3I [2] reactions was studied by laser-induced fluorescence. Product vibrational state distributions were obtained. It was also found that 19% and 16% of the exoergicity resides, respectively, in vibrational and rotational excitations of the CaI product from reaction [1], and 40% and 12%, respectively, from reaction [2]. The results are discussed in the context of various models, and product recoil momentum distributions have been estimated.


1986 ◽  
Vol 84 (9) ◽  
pp. 5213-5214 ◽  
Author(s):  
Nobuaki Nishiyama ◽  
Hiroshi Sekiya ◽  
Yukio Nishimura

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