Phase transitions of (1:1) alkaline salts of TCNQ as studied by vibronic intensity enhancement in the infrared spectra

1999 ◽  
Vol 67 (9) ◽  
pp. 3864 ◽  
Author(s):  
Renato Bozio
2021 ◽  
Vol 341 ◽  
pp. 117233
Author(s):  
Natalia Osiecka-Drewniak ◽  
Mirosław A. Czarnecki ◽  
Zbigniew Galewski

2020 ◽  
Vol 124 (42) ◽  
pp. 23307-23316
Author(s):  
Kirill N. Boldyrev ◽  
Vasilisa E. Anikeeva ◽  
Olga I. Semenova ◽  
Marina N. Popova

1979 ◽  
Vol 71 (11) ◽  
pp. 4614-4619 ◽  
Author(s):  
J. F. Rabolt ◽  
T. C. Clarke ◽  
G. B. Street

1989 ◽  
Vol 03 (11) ◽  
pp. 1671-1679 ◽  
Author(s):  
W.S. TSE ◽  
C.S. FANG ◽  
A. ANDERSON ◽  
B.H. TORRIE

Raman and infrared spectra of polycrystalline HI and DI in the region of lattice and internal modes for all three phases have been recorded over the temperature range 18 K to the melting point. The temperature dependent Raman and infrared results are consistent with the X-ray and neutron work that two phase transitions occur at HI and DI involving reorientation of the HI and DI molecules as a whole.


1983 ◽  
Vol 98 (1) ◽  
pp. 175-182 ◽  
Author(s):  
A. D. Laskovetz ◽  
I. I. Gorina ◽  
L. S. Gorbatenko ◽  
I. G. Chistyakov ◽  
G. V. Mikhailenko

1984 ◽  
Vol 37 (1) ◽  
pp. 23 ◽  
Author(s):  
SD Hamann ◽  
P Mazerolles ◽  
A Faucher ◽  
G Manuel

Measurements have been made of the infrared spectra of eight solid heterocyclic organosilicon and organogermanium compounds at pressures up to 5 GPa at normal temperature. Evidence is found of reversible conformational changes under pressure, and of phase transitions in some of the compounds. Unexpectedly, it appears that compression does not favour the transannular interaction that exists, in some cases, between the heteroatom (silicon or germanium) and a functional group on the opposite side of the ring.


1964 ◽  
Vol 42 (1) ◽  
pp. 57-62 ◽  
Author(s):  
A. Théorêt ◽  
C. Sandorfy

The infrared spectra of solid crystalline films of ammonium nitrate were measured at temperatures ranging between the melting point (169 °C) and liquid air temperature (−190 °C). Four different spectra were obtained which are shown to belong to phase I, II, IV, and (very probably) VII. Phases III and V were not encountered; only transitions [Formula: see text], [Formula: see text], and [Formula: see text] were observed. A spectrum measured at −190 °C after rapid cooling is shown to correspond to a mixture of phases IV and VII. The symmetry properties of the different phases are discussed in relation with their infrared spectra.


1962 ◽  
Vol 40 (4) ◽  
pp. 615-621 ◽  
Author(s):  
A. Cabana ◽  
C. Sandorfy

The infrared spectra of solid films of piperidinium halides were measured at both room temperature and low temperatures. The spectra of the chloride and the bromide are not appreciably affected by cooling, but the spectrum of the iodide exhibits spectacular changes. These changes are explained by assuming the occurrence of a phase transition at about −15 °C. The possibility of a "chair" → "boat" interconversion is also discussed.


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