X‐ray and electron scattering from diatomic molecules in the first Born approximation

1977 ◽  
Vol 66 (9) ◽  
pp. 4057-4064 ◽  
Author(s):  
Joel Epstein ◽  
Robert F. Stewart
Keyword(s):  
Electron Scattering ◽  
Born Approximation ◽  
Diatomic Molecules ◽  
X Ray

Chemical modification of the bacterial wall to determine sites of metal deposition

1978 ◽  
Vol 36 (2) ◽  
pp. 350-351
Author(s):  
T. J. Beveridge
Keyword(s):  
Electron Scattering ◽  
Metal Salt ◽  
Metal Deposition ◽  
Suitable Model ◽  
X Ray Diffraction ◽  
Subtilis Cell ◽  
Thin Sections ◽  
X Ray ◽  
Section Data ◽  
Metal Impregnation

The Bacillus subtilis cell wall provides a protective sacculus about the vital constituents of the bacterium and consists of a collection of anionic hetero- and homopolymers which are mainly polysaccharidic. We recently demonstrated that unfixed walls were able to trap and retain substantial amounts of metal when suspended in aqueous metal salt solutions. These walls were briefly mixed with low concentration metal solutions (5mM for 10 min at 22°C), were well washed with deionized distilled water, and the quantity of metal uptake (atomic absorption and X-ray fluorescence), the type of staining response (electron scattering profile of thin-sections), and the crystallinity of the deposition product (X-ray diffraction of embedded specimens) determined.Since most biological material possesses little electron scattering ability electron microscopists have been forced to depend on heavy metal impregnation of the specimen before obtaining thin-section data. Our experience with these walls suggested that they may provide a suitable model system with which to study the sites of reaction for this metal deposition.

Artefacts in the x-ray microanalysis of frozen-hydrated biological samples

1987 ◽  
Vol 45 ◽  
pp. 658-659
Author(s):  
Patrick Echlin
Keyword(s):  
Electron Scattering ◽  
Biological Samples ◽  
Fracture Face ◽  
Detailed Structure ◽  
X Ray ◽  
Morphological Appearance ◽  
The Poor ◽  
Freeze Dried

A number of papers have appeared recently which purport to have carried out x-ray microanalysis on fully frozen hydrated samples. It is important to establish reliable criteria to be certain that a sample is in a fully hydrated state. The morphological appearance of the sample is an obvious parameter because fully hydrated samples lack the detailed structure seen in their freeze dried counterparts. The electron scattering by ice within a frozen-hydrated section and from the surface of a frozen-hydrated fracture face obscures cellular detail. (Fig. 1G and 1H.) However, the morphological appearance alone can be quite deceptive for as Figures 1E and 1F show, parts of frozen-dried samples may also have the poor morphology normally associated with fully hydrated samples. It is only when one examines the x-ray spectra that an assurance can be given that the sample is fully hydrated.

Extended Core Edge Fine Structure in the E.M.

1980 ◽  
Vol 38 ◽  
pp. 120-121
Author(s):  
R.D. Leapman
Keyword(s):  
Fine Structure ◽  
Electron Scattering ◽  
Inelastic Electron ◽  
High Resolution Imaging ◽  
X Ray ◽  
Analytical Electron ◽  
Analytical Electron Microscope ◽  
Core Electrons ◽  
Resolution Imaging ◽  
X Ray Absorption

Extended X-ray Absorption Fine Structure (EXAFS) analysis makes use of synchrotron radiaion to measure modulations in the absorption coefficient above core edges and hence to obtain information about local atomic environments. EXAFS arises when ejected core electrons are backscattered by surrounding atoms and interfere with the outgoing waves. Recently, interest has also been shown in using inelastic electron scattering1-4. Some advantages of Extended X-ray-edge Energy Loss Fine Structure (EXELFS) are: a) small probes formed by the analytical electron microscope give spectra from μm to nm sized areas, compared with mm diameter areas for the X-ray technique, b) EXELFS can be combined with other techniques such as electron diffraction or high resolution imaging, and c) EXELFS is sensitive to low Z elements with K edges from ˜200 eV to ˜ 3000 eV (B to Cl).

Halogens molecular modifications with high pressure: the case of iodine

2021 ◽  
Author(s):  
Jingming Shi ◽  
Emiliano Fonda ◽  
Silvana Botti ◽  
Miguel A. L. Marques ◽  
Toru Shinmei ◽  
...  
Keyword(s):  
High Pressure ◽  
Absorption Spectroscopy ◽  
Diatomic Molecules ◽  
Giant Planets ◽  
Atomistic Modeling ◽  
X Ray ◽  
X Ray Absorption

Metallization and dissociation are key transformations in diatomic molecules at high densities particularly significant for modeling giant planets. Using X-ray absorption spectroscopy and atomistic modeling, we demonstrate that in halogens,...

scholarly journals Effects of Compton scattering on the neutron star radius constraints in rotation-powered millisecond pulsars

2019 ◽  
Vol 627 ◽  
pp. A39 ◽  
Author(s):  
Tuomo Salmi ◽  
Valery F. Suleimanov ◽  
Juri Poutanen
Keyword(s):  
Angular Distribution ◽  
Neutron Star ◽  
Energy Spectrum ◽  
Compton Scattering ◽  
Electron Scattering ◽  
Exact Formulation ◽  
Millisecond Pulsars ◽  
X Ray ◽  
Synthetic Phase ◽  
Neutron Star Radius

The aim of this work is to study the possible effects and biases on the radius constraints for rotation-powered millisecond pulsars when using Thomson approximation to describe electron scattering in the atmosphere models, instead of using exact formulation for Compton scattering. We compare the differences between the two models in the energy spectrum and angular distribution of the emitted radiation. We also analyse a self-generated, synthetic, phase-resolved energy spectrum, based on Compton atmosphere and the most X-ray luminous, rotation-powered millisecond pulsars observed by the Neutron star Interior Composition ExploreR (NICER). We derive constraints for the neutron star parameters using both the Compton and Thomson models. The results show that the method works by reproducing the correct parameters with the Compton model. However, biases are found in both the size and the temperature of the emitting hotspot, when using the Thomson model. The constraints on the radius are still not significantly changed, and therefore the Thomson model seems to be adequate if we are interested only in the radius measurements using NICER.

Parallel Monte Carlo Simulation Using Desktop Computers

1999 ◽  
Vol 5 (S2) ◽  
pp. 80-81
Author(s):  
John Henry J. Scott ◽  
Robert L. Myklebust ◽  
Dale E. Newbury
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Electron Scattering ◽  
Information Needs ◽  
Image Interpretation ◽  
Scattered Electron ◽  
Electron Trajectories ◽  
X Ray ◽  
Desktop Computers ◽  
Computationally Expensive

Monte Carlo simulation of electron scattering in solids has proven valuable to electron microscopists for many years. The electron trajectories, x-ray generation volumes, and scattered electron signals produced by these simulations are used in quantitative x-ray microanalysis, image interpretation, experimental design, and hypothesis testing. Unfortunately, these simulations are often computationally expensive, especially when used to simulate an image or survey a multidimensional region of parameter space.Here we present techniques for performing Monte Carlo simulations in parallel on a cluster of existing desktop computers. The simulation of multiple, independent electron trajectories in a sample and the collateral calculation of detected x-ray and electron signals falls into a class of computational problems termed “embarrassingly parallel”, since no information needs to be exchanged between parallel threads of execution during the calculation. Such problems are ideally suited to parallel multicomputers, where a manager process distributes the computational burden over a large number of nodes.

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