Brillouin scattering from liquid benzene at high pressures

1977 ◽  
Vol 66 (5) ◽  
pp. 1940-1942 ◽  
Author(s):  
F. D. Medina ◽  
D. C. O’Shea
2010 ◽  
Vol 133 (4) ◽  
pp. 044503 ◽  
Author(s):  
Min Li ◽  
Fangfei Li ◽  
Wei Gao ◽  
Chunli Ma ◽  
Liyin Huang ◽  
...  

2019 ◽  
Vol 104 (11) ◽  
pp. 1650-1655
Author(s):  
Wei Wei ◽  
Xinyang Li ◽  
Ningyu Sun ◽  
Sergey N. Tkachev ◽  
Zhu Mao

Abstract In this study, we have determined the combined effect of pressure and temperature on the compressional-wave velocity (VP) of Ne up to 53 GPa and 1100 K using Brillouin scattering in externally heated diamond-anvil cells. The phase transition from the supercritical fluid to solid phase was observed to cause a 10.5–11% jump in VP, and the magnitude in the VP contrast across the phase transition increases with temperature. In addition, we have observed an abnormal reduced increase rate of VP with pressure in the supercritical Ne fluid at both 800 and 1100 K before the transition to the solid phase. VP of the solid Ne exhibits a nonlinear increase with pressure at all the investigated temperatures. The elevating temperature was noted to cause an apparent reduction in VP, yet the reduction in VP caused by increasing temperature dramatically decreases at higher pressures. At 20 GPa, increasing temperature by 100 K can lower the VP of Ne by 2.4%. Yet elevating temperature by 100 K can only reduce the VP by 0.4% at 50 GPa. We further compare VP of Ne to that of other rare gases, including Ar, Kr, and Xe. At 300 K, VP of Ne shows a stronger dependence on pressure than both Kr and Xe. Moreover, increasing temperature can produce a greater reduction in VP of Ne than that of Ar below 50 GPa. Our measured VP of Ne is also useful for understanding the velocity structure of giant planets, such as Jupiter.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
D. M. Dattelbaum ◽  
E. B. Watkins ◽  
M. A. Firestone ◽  
R. C. Huber ◽  
R. L. Gustavsen ◽  
...  

AbstractBenzene (C6H6), while stable under ambient conditions, can become chemically reactive at high pressures and temperatures, such as under shock loading conditions. Here, we report in situ x-ray diffraction and small angle x-ray scattering measurements of liquid benzene shocked to 55 GPa, capturing the morphology and crystalline structure of the shock-driven reaction products at nanosecond timescales. The shock-driven chemical reactions in benzene observed using coherent XFEL x-rays were a complex mixture of products composed of carbon and hydrocarbon allotropes. In contrast to the conventional description of diamond, methane and hydrogen formation, our present results indicate that benzene’s shock-driven reaction products consist of layered sheet-like hydrocarbon structures and nanosized carbon clusters with mixed sp2-sp3 hybridized bonding. Implications of these findings range from guiding shock synthesis of novel compounds to the fundamentals of carbon transport in planetary physics.


1981 ◽  
Vol 74 (1) ◽  
pp. 1-3 ◽  
Author(s):  
A. Asenbaum ◽  
H. D. Hochheimer

1980 ◽  
Vol 15 (5) ◽  
pp. 403-409 ◽  
Author(s):  
V. P. Arkhipov ◽  
N. K. Gaisin

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