The thermodynamics of ionization of gaseous oxides; the first ionization potentials of the lanthanide metals and monoxides

1976 ◽  
Vol 65 (3) ◽  
pp. 1027-1031 ◽  
Author(s):  
R. J. Ackermann ◽  
E. G. Rauh ◽  
R. J. Thorn
Keyword(s):  
Ionization Potentials ◽  
Lanthanide Metals ◽  
Thermodynamics Of Ionization

scholarly journals A Dy(III) Fluorescent Single-Molecule Magnet Based on a Rhodamine 6G Ligand

Inorganics ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 51
Author(s):  
Lin Miao ◽  
Mei-Jiao Liu ◽  
Man-Man Ding ◽  
Yi-Quan Zhang ◽  
Hui-Zhong Kou
Keyword(s):  
Magnetic Properties ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Rhodamine 6G ◽  
Bond Angle ◽  
Magnetic Measurements ◽  
Single Molecule Magnet ◽  
Lanthanide Metals ◽  
Process Studies ◽  
Dual Functions

The complexes of lanthanide metals, especially dysprosium, can generally exhibit excellent magnetic properties. By means of modifying ligands, dual functions or even multi-functions can be achieved. Here, we synthesized an eight-coordinate Dy(III) complex 1, [Dy(HL-o)2(MeOH)2](ClO4)3·4.5MeOH, which is single-molecule magnet (SMM), and the introduction of the rhodamine 6G chromophore in the ring-opened ligand HL-o realizes ligand-centered fluorescence in addition to SMM. Magnetic measurements and ab initio calculations indicate that the magnetic relaxation for complex 1 should be due to the Raman relaxation process. Studies on magneto-structural correlationship of the rhodamine salicylaldehyde hydrazone Dy(III) complexes show that the calculated energy of the first Kramers Doublet (EKD1) is basically related to the Ophenoxy-Dy-Ophenoxy bond angle, i.e., the larger Ophenoxy-Dy-Ophenoxy bond angle corresponds to a larger EKD1.

The ionization potentials of CH4 and CD4

1987 ◽  
Vol 86 (2) ◽  
pp. 674-676 ◽  
Author(s):  
J. Berkowitz ◽  
J. P. Greene ◽  
H. Cho ◽  
B. Ruscić
Keyword(s):  
Ionization Potentials
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