Lithium isotope separation factors of some two‐phase equilibrium systems

1976 ◽  
Vol 64 (4) ◽  
pp. 1828-1837 ◽  
Author(s):  
A. A. Palko ◽  
J. S. Drury ◽  
G. M. Begun
2010 ◽  
Vol 65 (5) ◽  
pp. 461-467 ◽  
Author(s):  
Keita Zenzai ◽  
Ayaka Yasui ◽  
Satoshi Yanase ◽  
Takao Oi

Lithium was electrochemically inserted from a 1 : 2 (v/v) mixed solution of ethylene carbonate (EC) and methylethyl carbonate (MEC) containing 1M LiClO4 into liquid gallium to observe lithium isotope effects accompanying the insertion. It was observed that the lighter isotope 6Li was preferentially fractionated into liquid gallium with the single-stage lithium isotope separation factors S, ranging from 1.005 to 1.031 at 50 °C and 1.003 to 1.024 at 25 °C. The lithium isotope effects estimated by molecular orbital calculations at the B3LYP/6-311G(d) level of theory agreed qualitatively with those of the experiments, but the quantitative agreement of the two was not satisfactory


2016 ◽  
Vol 873 ◽  
pp. 18-22
Author(s):  
Ming Li Huang ◽  
Xue Shen ◽  
Hong Xiao Li

The equilibrium alloys closed to Mg-Nd side in the Mg-rich corner of the Mg-Zn-Nd system at 400°C have been investigated by scanning electron microscopy, electron probe microanalysis and X-ray diffraction. The binary solid solutions Mg12Nd and Mg3Nd with the solubility of Zn have been identified. The maximum solubility of Zn in Mg12Nd is 4.8at%, and Mg12Nd phase can be in equilibrium with Mg solid solution. However, only when the solubility range of Zn in 26at%~32.2at%, Mg3Nd can be in two-phase equilibrium with Mg solid solution. As the results, two two-phase regions as Mg+Mg12Nd and Mg+Mg3Nd and a three-phase region as Mg+Mg12Nd+Mg3Nd in Mg-Nd-Zn ternary isothermal section at 400°C have been identified.


2007 ◽  
Vol 633 (5-6) ◽  
pp. 858-864 ◽  
Author(s):  
Zacharias Grote ◽  
Hans-Dieter Wizemann ◽  
Rosario Scopelliti ◽  
Kay Severin

The liquid-vapour equilibrium of the system methane-ethylene has been determined at 0, -42 , -78, -88 and -104° C over a wide range of pressures and the results are shown on a pressure-composition-temperature diagram and by a series of pressure-composition curves. The liquid-vapour equilibrium of the ternary system methane-ethane-ethylene has been determined at -104, -78 and 0° C. Values for the two binary systems methane-ethane and methane-ethylene and for the ternary system methane-ethane-ethylene are shown on a composite pressure-composition diagram.


1991 ◽  
Vol 138 (8) ◽  
pp. L26-L27 ◽  
Author(s):  
T. R. Guilinger ◽  
M. J. Kelly ◽  
J. A. Knapp ◽  
D. S. Walsh ◽  
B. L. Doyle

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