Water vapor dependence of the kinetics of the self‐reaction of HO2 in the gas phase

1975 ◽  
Vol 63 (8) ◽  
pp. 3682-3683 ◽  
Author(s):  
E. J. Hamilton
Keyword(s):  
The Self ◽  
Author(s):  
T. Beiderhase ◽  
Walter Hack ◽  
Karlheinz Hoyermann ◽  
Matthias Olzmann

Fluorinated hydrocarbon radical-radical reactions in the gas phase have been studied at low pressure (0.5 ≤ p/mbar ≤ 2) and low temperature (253 ≤ T/K ≤ 333) using the discharge flow reactor molecular beam sampling mass spectrometry (MS) technique. Stable and labile species have been detected by MS applying low energy electron impact as well as multiphoton ionisation.For the combination reactionCHthe rate coefficient kCHis the main channel (k(1b)/kFor the CHFCHFthe rate coefficient was measured as kNo pressure dependence of k


2020 ◽  
Vol 22 (39) ◽  
pp. 22436-22450
Author(s):  
Shun Iwasaki ◽  
Nobuyoshi Koga

The reaction pathway and kinetics of thermal dehydration is regulated by the self-generated water vapor.


1993 ◽  
Vol 203 (2-3) ◽  
pp. 302-306 ◽  
Author(s):  
Ole J. Nielsen ◽  
Thomas Ellermann ◽  
Timothy J. Wallington

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