Pressure dependence of rotational relaxation times T1 and T2 in the J=0−1 transition of OCS

1975 ◽  
Vol 63 (12) ◽  
pp. 5145-5152 ◽  
Author(s):  
Stephen L. Coy
1979 ◽  
Vol 34 (10) ◽  
pp. 1181-1184
Author(s):  
H. Mäder ◽  
W. Lalowski ◽  
R. Schwarz

Abstract The dependence of rotational relaxation times T1 and T2 on pressure and temperature has been determined for various rotational transitions of ethylene oxide by using transient microwave techniques.


1980 ◽  
Vol 35 (11) ◽  
pp. 1197-1200
Author(s):  
A. Kawski ◽  
Z. Kojro ◽  
M. Alicka

Abstract The fluorescence anisotropics (FA) r and the lifetimes of p-terphenyl in different solvents have been measured, the effective volumes and the rotational relaxation times being determined. The deviation from the linear dependence of 1/r on 1/η (η-viscosity of the solvent) may explained by the length of the p-terphenyl molecule. The FA measurements were carried out by a method with an Arago compensator, a new method of the automatization of measurements being employed.


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