A study of the dynamic behavior of the vibrational population relaxation in carbon monoxide

1975 ◽  
Vol 63 (1) ◽  
pp. 235-240 ◽  
Author(s):  
Yung S. Liu ◽  
R. A. McFarlane ◽  
G. J. Wolga
1977 ◽  
Vol 52 (2) ◽  
pp. 208-212 ◽  
Author(s):  
Joseph N. Kushick ◽  
Stuart A. Rice

1973 ◽  
Vol 51 (3) ◽  
pp. 451-455
Author(s):  
S. J. Arnold ◽  
G. H. Kimbell

Infrared chemiluminescence attributed to the first overtone of CO was observed when either C2H2 or was introduced into a stream of oxygen which had been passed through a microwave discharge. The addition of vibrationally cold CO to these systems was found to produce a vibrational population inversion in the chemically formed CO. CO first overtone emission was not observed when CH4 was introduced into a similar stream of oxygen unless the CH4 had been subjected to a microwave discharge. These observations are used to clarify the mechanisms governing the formation of CO in continuous wave air–helium–hydrocarbon electrical discharge lasers.


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