Criterion for excess electron localization in liquid alkanes

1975 ◽  
Vol 62 (7) ◽  
pp. 2914-2915 ◽  
Author(s):  
Kenji Fueki ◽  
Larry Kevan
Keyword(s):  
Excess Electron ◽  
Electron Localization ◽  
Liquid Alkanes

Effect of density on excess electron localization in ethane and propane

1977 ◽  
Vol 66 (1) ◽  
pp. 366-367 ◽  
Author(s):  
Toyoaki Kimura ◽  
Kenji Fueki
Keyword(s):  
Excess Electron ◽  
Electron Localization

Turning on the triplet state channel in the excess electron scavenging by nitroxyl radicals in liquid alkanes

2012 ◽  
Vol 531 ◽  
pp. 86-89 ◽  
Author(s):  
Vsevolod I. Borovkov ◽  
Irina S. Ivanishko ◽  
Irina V. Beregovaya ◽  
Vladimir A. Reznikov
Keyword(s):  
Triplet State ◽  
Nitroxyl Radicals ◽  
Excess Electron ◽  
Liquid Alkanes

On excess electron localization in ethane clusters

1979 ◽  
Vol 70 (8) ◽  
pp. 3997-3998 ◽  
Author(s):  
Toyoaki Kimura ◽  
Kenji Fueki
Keyword(s):  
Excess Electron ◽  
Electron Localization

Dynamics of Excess Electron Localization in Liquid Helium and Neon

1997 ◽  
Vol 101 (4) ◽  
pp. 751-757 ◽  
Author(s):  
Michael Rosenblit ◽  
Joshua Jortner
Keyword(s):  
Liquid Helium ◽  
Excess Electron ◽  
Electron Localization

Evidence for New Excess Electron Localization Sites inNanFn−1Alkali-Halide Clusters

1997 ◽  
Vol 79 (4) ◽  
pp. 633-636 ◽  
Author(s):  
G. Durand ◽  
F. Spiegelmann ◽  
P. Labastie ◽  
J.-M. L'Hermite ◽  
Ph. Poncharal
Keyword(s):  
Excess Electron ◽  
Electron Localization

A semicontinuum model with a structured first solvation shell for excess electrons in liquid and glassy alkanes

1977 ◽  
Vol 55 (11) ◽  
pp. 1940-1951 ◽  
Author(s):  
Toyoaki Kimura ◽  
Kenji Fueki ◽  
P. A. Narayana ◽  
Larry Kevan
Keyword(s):  
Molecular Structure ◽  
Experimental Data ◽  
Spin Echo ◽  
Electron Spin Echo ◽  
Solvation Shell ◽  
Electron Interaction ◽  
Electron Localization ◽  
Mobility Data ◽  
Excess Electrons ◽  
Liquid Alkanes

The microdipole model for excess electrons in alkanes seems inconsistent with recent electron spin echo data. We develop a new model for electron binding in alkanes based on a semi-continuum potential framework in which the electron-polarizability energy is dependent on molecular structure by considering the electron interaction with the polarizability of each C—C bond of the first solvation shell molecules rather than with point molecules. In addition we incorporate the effect of hydrogen–hydrogen repulsion between first solvation shell molecules. This model accounts well for the variety of experimental data known for localized electrons in 3-methylpentane glass at 77 K and for electron localization or nonlocalization in various liquid alkanes consistent with electron mobility data.

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