Infrared spectra of matrix isolated alkali metal perchlorate ion pairs

1975 ◽  
Vol 62 (5) ◽  
pp. 1982-1986 ◽  
Author(s):  
Gary Ritzhaupt ◽  
J. Paul Devlin
Keyword(s):  
Alkali Metal ◽  
Infrared Spectra ◽  
Ion Pairs ◽  
Perchlorate Ion ◽  
Metal Perchlorate

Matrix spectra, force constants, and structures for M+ClO4- and hydrated alkali metal perchlorate ion pairs

1979 ◽  
Vol 18 (7) ◽  
pp. 1808-1811 ◽  
Author(s):  
Jon Draeger ◽  
Gary Ritzhaupt ◽  
J. Paul Devlin
Keyword(s):  
Alkali Metal ◽  
Ion Pairs ◽  
Force Constants ◽  
Perchlorate Ion ◽  
Metal Perchlorate

Infrared spectra of cyclopentadienyl-alkali metal (Li, Na) ion pairs in tetrahydrofuran and hexamethylphosphoric triamide

1987 ◽  
Vol 336 (1-2) ◽  
pp. 13-22 ◽  
Author(s):  
O.G. Garkusha ◽  
I.A. Garbuzova ◽  
B.V. Lokshin ◽  
A.N. Nesmeyanov ◽  
G.K. Borisov
Keyword(s):  
Alkali Metal ◽  
Infrared Spectra ◽  
Ion Pairs ◽  
Hexamethylphosphoric Triamide

Solution Properties of Tetraalkylammonium Halide and Alkali-Metal Halide Ion Pairs. The Relationship Between Dissociation Constants and Solubility Products

1987 ◽  
Vol 40 (7) ◽  
pp. 1201 ◽  
Author(s):  
W Mizerski ◽  
MK Kalinowski
Keyword(s):  
Alkali Metal ◽  
Solubility Product ◽  
Dissociation Constants ◽  
Ion Pairs ◽  
Empirical Relation ◽  
Alkali Metal Halide ◽  
Alkali Metal Cations ◽  
Solubility Products ◽  
The Relationship ◽  
Dissociation Constant Kd

An empirical relation describing the effect of solvent on the dissociation constant ( Kd ) of ion pairs is described. An equation of the form pKd = apKso + bD-1 + c ( Kso and D stand for the solubility product of a given salt and for the electric permittivity of a solvent, respectively) has been tested with 13 sets of experimental data for salts containing tetraalkylammonium and alkali-metal cations. A successful correlation was obtained in 100% of the cases considered.

Axle component separated ion-pair recognition by a neutral heteroditopic [2]rotaxane

2014 ◽  
Vol 50 (13) ◽  
pp. 1540-1542 ◽  
Author(s):  
Richard C. Knighton ◽  
Paul D. Beer
Keyword(s):  
Alkali Metal ◽  
Metal Cation ◽  
Alkali Metal Cation ◽  
Ion Pairs ◽  
Ion Pair ◽  
Sodium Cation ◽  
Halide Anion ◽  
Cooperative Recognition

A neutral heteroditopic pyridine N-oxide axle containing [2]rotaxane, synthesised via sodium cation templation, displays cooperative recognition of alkali metal cation-halide anion ion-pairs in an unprecedented axle component separated ion-pair binding fashion.

Infrared spectra of the M+BrF2- and M+IF2- ion pairs in solid argon

1979 ◽  
Vol 18 (4) ◽  
pp. 988-992 ◽  
Author(s):  
J. Houston Miller ◽  
Lester Andrews
Keyword(s):  
Infrared Spectra ◽  
Ion Pairs ◽  
Solid Argon
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