Si–H bonding in low hydrogen content amorphous silicon films as probed by infrared spectroscopy and x-ray diffraction

2000 ◽  
Vol 87 (4) ◽  
pp. 1650-1658 ◽  
Author(s):  
A. H. Mahan ◽  
L. M. Gedvilas ◽  
J. D. Webb
Keyword(s):  
Infrared Spectroscopy ◽  
Amorphous Silicon ◽  
Hydrogen Content ◽  
Silicon Films ◽  
X Ray Diffraction ◽  
X Ray

Crystallization study of chemically vapour-deposited amorphous silicon films by in situ x-ray diffraction

1985 ◽  
Vol 124 (2) ◽  
pp. 171-177 ◽  
Author(s):  
R. Bisaro ◽  
N. Proust ◽  
J. Magariño ◽  
K. Zellama
Keyword(s):  
Amorphous Silicon ◽  
Silicon Films ◽  
X Ray Diffraction ◽  
X Ray ◽  
Crystallization Study

scholarly journals Valorization of Byproducts of Hemp Multipurpose Crop: Short Non-Aligned Bast Fibers as a Source of Nanocellulose

Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4723
Author(s):  
Sara Dalle Vacche ◽  
Vijayaletchumy Karunakaran ◽  
Alessia Patrucco ◽  
Marina Zoccola ◽  
Loreleï Douard ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Thermogravimetric Analysis ◽  
Cannabis Sativa ◽  
Crystallinity Index ◽  
Residual Lignin ◽  
Chemical Pretreatment ◽  
X Ray Diffraction ◽  
X Ray ◽  
Bast Fibers ◽  
Seed Maturity

Nanocellulose was extracted from short bast fibers, from hemp (Cannabis sativa L.) plants harvested at seed maturity, non-retted, and mechanically decorticated in a defibering apparatus, giving non-aligned fibers. A chemical pretreatment with NaOH and HCl allowed the removal of most of the non-cellulosic components of the fibers. No bleaching was performed. The chemically pretreated fibers were then refined in a beater and treated with a cellulase enzyme, followed by mechanical defibrillation in an ultrafine friction grinder. The fibers were characterized by microscopy, infrared spectroscopy, thermogravimetric analysis and X-ray diffraction after each step of the process to understand the evolution of their morphology and composition. The obtained nanocellulose suspension was composed of short nanofibrils with widths of 5–12 nm, stacks of nanofibrils with widths of 20–200 nm, and some larger fibers. The crystallinity index was found to increase from 74% for the raw fibers to 80% for the nanocellulose. The nanocellulose retained a yellowish color, indicating the presence of some residual lignin. The properties of the nanopaper prepared with the hemp nanocellulose were similar to those of nanopapers prepared with wood pulp-derived rod-like nanofibrils.

Synthesis and Crystal Structure of the Flexible Ligand Coordination Polymer [Co3(bpd)5.5(NCS)6(NH3)]n⋅2H2O(bpd= 1,4-bis (4-pyridyl)-2,3-diaza-1,3-butadiene)

2013 ◽  
Vol 803 ◽  
pp. 80-84
Author(s):  
Yu Qi Liu ◽  
Yong Yang ◽  
Rui Yang ◽  
Xiao Jun Xu
Keyword(s):  
Crystal Structure ◽  
Infrared Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Elemental Analyses ◽  
Ligand Coordination ◽  
Point Symbol

A novel metalorganic coordination polymer, namely [Co3(bpd)5.5(NCS)6(NH3)]n2H2O (1) (bpd=1,4-bis (4-pyridyl)-2,3-diaza-1,3-butadiene), has been synthesized and characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. Compound 1 presents 2D[3,4,-connected 3-nodal net with the point symbol (4268210)(4462)(8210). In addition, four identical 2D single nets is interlocked with each other in parallel, thus directly leading to the formation of a polycatenated layer (2D2D).

Synthesis, Characterization and Thermal Behavior of  HYP2O7·3H2O Electrical Properties of  HYP2O7

2021 ◽  
Author(s):  
Rahma Rahzelli Zrelli ◽  
Fathia Chehimi-Moumen ◽  
Dalila Ben Hassen-Chehimi ◽  
Malika Trabelsi-Ayadi
Keyword(s):  
Infrared Spectroscopy ◽  
Electrical Properties ◽  
Complex Analysis ◽  
Optical Band Gap ◽  
Water Molecules ◽  
X Ray Diffraction ◽  
Soft Chemistry ◽  
Medium Temperature ◽  
X Ray ◽  
Three Stages

Abstract The synthesis of the diphosphate HYP2O7·3H2O was made via soft chemistry route from evaporation of aqueous solution at room temperature. The obtained compound, was characterized by means of X-ray diffraction (XRD) and infrared spectroscopy (IR). The results showed a high purity phase. IR spectrum of this diphosphate revealed usual signals related to P2O7 diphosphate group and water molecules. The thermal decomposition of the synthesized product by DTA / TG proceeded through four stages leading to the formation of the Y2P4O13 as a final product. On the other hand, its decomposition by CRTA took place in three stages leading to the formation of the anhydrous diphosphate HYP2O7 as a final product. X-ray powder diffraction and infrared spectroscopy were used to identify these materials. Furthermore the electrical properties of the HYP2O7 were investigated through impedance complex analysis. Modest conductivity has been observed in this material at relatively medium temperature range. Activation energy of 0.67 and 1.44 eV, was deduced from the corresponding Arrhenius plot.The optical band gap of the title compound is calculated and found to be 2.71 eV.

Preparation of Borosilicate Xerogel and Research on its Mineralization

2012 ◽  
Vol 476-478 ◽  
pp. 2059-2062
Author(s):  
Chen Wang ◽  
Ya Dong Li ◽  
Gu Qiao Ding
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Ph Value ◽  
Sol Gel ◽  
X Ray Diffraction ◽  
X Ray ◽  
Compositional Changes ◽  
Scanning Electron

Tributyl borate was first adopted for the introduction of boron in the preparation of bioactive borosilicate xerogel by sol-gel method. The xerogel reacted continuously in 0.25M K2HPO4 solution with a starting pH value of 7.0 at 37 °C for 1day. The structural, morphologies and compositional changes resulting from the conversion were characterized using X-ray diffraction, scanning electron microscopy and Fourier transform infrared spectroscopy. The results indicated that speed of formation of HA was cut way back on the time with the addition of boron and the induction period for the HA nucleation on the surface of the borosilicate xerogel was short than 1 days. The conversion mechanism of the borosilicate xerogels to hydroxyapaptite was also discussed.

scholarly journals Mineralogical stabilization of Ternesite in Belite Sulfo-Aluminate Clinker elaborated from limestone, shale and phosphogypsum

2018 ◽  
Vol 149 ◽  
pp. 01073
Author(s):  
K. Ben Addi ◽  
A. Diouri ◽  
N. Khachani ◽  
A. Boukhari
Keyword(s):  
Infrared Spectroscopy ◽  
Phosphoric Acid ◽  
Portland Cement ◽  
Stability Conditions ◽  
X Ray Diffraction ◽  
X Ray ◽  
The Stability

This paper investigates the mineralogical evolution of sulfoaluminate clinker elaborated from moroccan prime materials limestone, shale and phosphogypsum as a byproduct from phosphoric acid factories. The advantage of the production of this type of clinker is related to the low clinkerisation temperature which is known around 1250°C, and to less consumption quantity of limestone thus enabling less CO2 emissions during the decarbonation process compared to that of Portland cement. In this study we determine the stability conditions of belite sulfoaluminate clinker containing belite (C2S) ye’elimite (C4A3$) and ternesite (C5S2$). The hydration compounds of this clinker are also investigated. The monitoring of the synthesized and hydrated phases is performed by X-Ray Diffraction and Infrared spectroscopy. The results show the formation of ternesite at 800°C and the stabilization of clinker containing y’elminite, belite and ternesite at temperatures between 1100 and 1250°C.

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