Fullerene acceptor for improving open-circuit voltage in inverted organic photovoltaic devices without accompanying decrease in short-circuit current density

2012 ◽  
Vol 100 (6) ◽  
pp. 063303 ◽  
Author(s):  
Yutaka Matsuo ◽  
Junichi Hatano ◽  
Takayuki Kuwabara ◽  
Kohshin Takahashi
Keyword(s):  
Current Density ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Organic Photovoltaic ◽  
Photovoltaic Devices ◽  
Organic Photovoltaic Devices

scholarly journals P3HT:PCBM Incorporated with Silicon Nanoparticles as Photoactive Layer in Efficient Organic Photovoltaic Devices

2013 ◽  
Vol 2013 ◽  
pp. 1-4 ◽  
Author(s):  
Shang-Chou Chang ◽  
Yu-Jen Hsiao ◽  
To-Sing Li
Keyword(s):  
Silicon Nanoparticles ◽  
Short Circuit ◽  
Acid Methyl Ester ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Organic Photovoltaic ◽  
Photovoltaic Devices ◽  
Organic Photovoltaic Devices ◽  
Photoactive Layer

Silicon nanoparticles doped poly(3-hexylthiophene) and [6,6]-phenyl C61-butyric acid methyl ester blends (P3HT:PCBM: Si NP) have been produced as the photoactive layer of organic photovoltaic devices (OPVs). The silicon nanoparticles’ size is between 80 and 100 nm checked by transmission electron microscope (TEM). The 0.35 wt% Si NP doping OPVs exhibit higher power conversion efficiency (PCE) than other OPVs. The PCE of the OPVs increases from 3.01% to 3.38% mainly due to increasing short-circuit current density from 8.38 to 9.48 mA/cm2, while the open-circuit voltage remains the same. The Si NP can provide extra exciton separation and electron pathways in hybrid solar cells.

IMPROVING STABILITY OF CHLOROPHYLL AS NATURAL DYE FOR DYE-SENSITIZED SOLAR CELLS

2017 ◽  
Vol 80 (1) ◽  
Author(s):  
Zainal Arifin ◽  
Sudjito Soeparman ◽  
Denny Widhiyanuriyawan ◽  
Suyitno Suyitno ◽  
Argatya Tara Setyaji
Keyword(s):  
Current Density ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Natural Dyes ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Natural dyes have attracted much researcher’s attention due to their low-cost production, simple synthesis processes and high natural abundance. However the dye-sensitized solar cells (DSSCs) based natural dyes have higher tendency to degradation. This article reports on the enhancement of performance and stability of dye-sensitized solar cells (DSSCs) using natural dyes. The natural dyes were extracted from papaya leaves by ethanol solvent at a temperature of 50 °C. Then the extracted dyes were isolated and modified into Mg-chlorophyll using column chromatography. Mg-chlorophyll was then synthesized into Fe-chlorophyll to improve stability. The natural dyes were characterized using ultraviolet-visible spectrometry, Fourier transform infrared spectroscopy, and cyclic voltammetry. The performance of DSSCs was tested using a solar simulator. The results showed the open-circuit voltage, the short-circuit current density, and the efficiency of the extracted papaya leaves-based DSSCs to be 325 mV, 0.36 mA/cm2, and 0.07%, respectively. Furthermore, the DSSCs with purified chlorophyll provide high open-circuit voltage of 425 mV and short-circuit current density of 0.45 mA/cm2. The use of Fe-chlorophyll for sensitizing the DSSCs increases the efficiency up to 2.5 times and the stability up to two times. The DSSCs with Fe-chlorophyll dyes provide open-circuit voltage, short-circuit current density, and efficiency of 500 mV, 0.62 mA/cm2, and 0.16%, respectively. Further studies to improve the current density and stability of natural dye-based DSSCs along with an improvement in the anchor between dyes and semiconducting layers are required.

Optimum driving energy for achieving balanced open-circuit voltage and short-circuit current density in organic bulk heterojunction solar cells

2018 ◽  
Vol 20 (47) ◽  
pp. 29866-29875 ◽  
Author(s):  
Wenchao Yang ◽  
Yao Yao ◽  
Pengfei Guo ◽  
Haibin Sun ◽  
Yongsong Luo
Keyword(s):  
Current Density ◽  
Open Circuit Voltage ◽  
Bulk Heterojunction ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Model Calculations ◽  
Heterojunction Solar Cells ◽  
Device Model

Device model calculations show that balanced Jsc and Voc can be achieved at an optimum driving energy of 0.2 eV.

Effect of Assets of Silicon Film Passivation Layer on the Performance of Silicon Nanowire Solar Cells

2014 ◽  
Vol 633-634 ◽  
pp. 509-512
Author(s):  
Ping Yang ◽  
Xiang Bo Zeng ◽  
Xiao Dong Zhang ◽  
Zhan Guo Wang
Keyword(s):  
Solar Cell ◽  
Current Density ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Silicon Film ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Passivation Layer ◽  
Hydrogen Dilution

Silicon film as a surface passivation layer is reported to reduce surface recombination on silicon nanowires (SiNWs) and thus enable to improve SiNW solar cell (SC) performance. A question yet to be answered regards the link between the silicon film assets and the solar cell performances. We investigated the effect of the properties of silicon films on the SiNWs SC performances by adjusting hydrogen dilution. Our results showed that the open-circuit voltage (Voc) and short-circuit current density (Jsc) of SiNWs SC increase until hydrogen dilution 10 and then decrease. An open-circuit voltage of 0.397 V and short-circuit current density of 18.42 mA/cm2 are achieved at optimized hydrogen dilution. Based on the analysis of silicon film properties we proposed that the increase of defect density with hydrogen dilution was the main cause for the deterioration of SiNWs SC performance.

Simultaneous Enhancement of Open-Circuit Voltage, Short-Circuit Current Density, and Fill Factor in Polymer Solar Cells

2011 ◽  
Vol 23 (40) ◽  
pp. 4636-4643 ◽  
Author(s):  
Zhicai He ◽  
Chengmei Zhong ◽  
Xun Huang ◽  
Wai-Yeung Wong ◽  
Hongbin Wu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Current Density ◽  
Fill Factor ◽  
Open Circuit Voltage ◽  
Polymer Solar Cells ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit

Demonstration of a 4H SiC Betavoltaic Cell

2006 ◽  
Vol 527-529 ◽  
pp. 1351-1354 ◽  
Author(s):  
M.V.S. Chandrashekhar ◽  
Christopher I. Thomas ◽  
Hui Li ◽  
Michael G. Spencer ◽  
Amit Lal
Keyword(s):  
Current Density ◽  
Fill Factor ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Type Model ◽  
Good Correspondence ◽  
Betavoltaic Cell

A betavoltaic cell in 4H SiC is demonstrated. An abrupt p-n diode structure was used to collect the charge from a 1mCi Ni-63 source. An open circuit voltage of 0.95V and a short circuit current density of 8.8 nA/cm2 were measured in a single p-n junction. An efficiency of 3.7% was obtained. A simple photovoltaic type model was used to explain the results. Good correspondence with the model was obtained. Fill factor and backscattering effects were included. Efficiency was limited by edge recombination and poor fill factor.

Synthesis and Photovoltaic Properties of Oligothiophene Derivatives with Liquid Crystal Properties

2010 ◽  
Vol 663-665 ◽  
pp. 832-835
Author(s):  
Li Guan ◽  
Juan Wang ◽  
Ming La ◽  
Yi Ping Zhong ◽  
Ping Liu ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Organic Photovoltaic ◽  
Photovoltaic Devices ◽  
Organic Photovoltaic Devices ◽  
Photovoltaic Properties ◽  
Photovoltaic Materials ◽  
Crystal Properties

For the purpose of developing novel photovoltaic materials and organic photovoltaic devices with good performance characteristics, 5-cyano-2,2′:5′,2″-terthiophene (3T-CN) and 5-cyano -2,2′:5′,2″:5″,2″′-tetrathiophene (4T-CN) were synthesized. The 3T-CN and 4T-CN was donor-acceeptor type oligothiophene derivatives with liquid crystal properties. The rigid and flexible photovoltaic devices were fabricated using 3T-CN, 4T-CN and 3,4,9,10-perylenetertracarboxylic dianhydride (PTCDA). Comparision of the rigid device based on 4T showed that both rigid device glass-ITO/4T-CN/PTCDA/Al and flexible device PET-ITO/4T-CN/PTCDA/Al had higher short circuit current density (Isc) and power conversion efficiency (PCE) than that of glass-ITO/4T /PTCDA/Al. The -CN group played an important role in increasing Isc and PCE. It is due to that the mesogenic properties of 4T-CN, which enhances the efficiency by promoting forward interfacial electron transfer.

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