Tuning the cation distribution and magnetic properties of single phase nanocrystalline Dy3Fe5O12 garnet

2012 ◽  
Vol 111 (7) ◽  
pp. 07A517 ◽  
Author(s):  
M. Guillot ◽  
C. N. Chinnasamy ◽  
J. M. Greneche ◽  
V. G. Harris
2015 ◽  
Vol 7 (1) ◽  
pp. 1346-1351
Author(s):  
Ch.Gopal Reddy ◽  
Ch. Venkateshwarlu ◽  
P. Vijaya Bhasker Reddy

Co-Zr substituted M-type hexagonal barium ferrites, with chemical formula BaCoxZrxFe12-2xO19 (where x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0), have been synthesized by double sintering ceramic method. The crystallographic properties, grain morphology and magnetic properties of these ferrites have been investigated by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Vibrating Sample Magnetometer (VSM). The XRD patterns confirm the single phase with hexagonal structure of prepared ferrites. The magnetic properties have been investigated as a function of Co and Zr ion composition at an applied field in the range of 20 KOe. These studies indicate that the saturation magnetization (Ms) in the samples increases initially up to the Co-Zr composition of x=0.6 and decreases thereafter. On the other hand, the coercivity (Hc) and Remanent magnetization (Mr) are found to decrease continuously with increasing Co-Zr content. This property is most useful in permanent magnetic recording. The observed results are explained on the basis of site occupation of Co and Zr ions in the samples.


Alloy Digest ◽  
1976 ◽  
Vol 25 (11) ◽  

Abstract METGLAS Alloy 2826 (Fe40Ni40P14B6) is a ferromagnetic, high permeability, nickel-iron metallic glass which, when appropriately annealed, yields a material similar to the higher nickel containing permalloys in magnetic properties. Alloy 2826 is a single phase, opaque metallic material with a glass-like structure obtained by a very rapid quench from the liquid state. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on forming and heat treating. Filing Code: Ni-235. Producer or source: Allied Chemical Corporation.


2021 ◽  
pp. 104112
Author(s):  
Sitchai Hunpratub ◽  
Sumalin Phokha ◽  
Pinit Kidkhunthod ◽  
Narong Chanlek ◽  
Prinya Chindaprasirt

Nano Research ◽  
2021 ◽  
Author(s):  
Alevtina Smekhova ◽  
Alexei Kuzmin ◽  
Konrad Siemensmeyer ◽  
Chen Luo ◽  
Kai Chen ◽  
...  

AbstractModern design of superior multi-functional alloys composed of several principal components requires in-depth studies of their local structure for developing desired macroscopic properties. Herein, peculiarities of atomic arrangements on the local scale and electronic states of constituent elements in the single-phase face-centered cubic (fcc)- and body-centered cubic (bcc)-structured high-entropy Alx-CrFeCoNi alloys (x = 0.3 and 3, respectively) are explored by element-specific X-ray absorption spectroscopy in hard and soft X-ray energy ranges. Simulations based on the reverse Monte Carlo approach allow to perform a simultaneous fit of extended X-ray absorption fine structure spectra recorded at K absorption edges of each 3d constituent and to reconstruct the local environment within the first coordination shells of absorbers with high precision. The revealed unimodal and bimodal distributions of all five elements are in agreement with structure-dependent magnetic properties of studied alloys probed by magnetometry. A degree of surface atoms oxidation uncovered by soft X-rays suggests different kinetics of oxide formation for each type of constituents and has to be taken into account. X-ray magnetic circular dichroism technique employed at L2.3 absorption edges of transition metals demonstrates reduced magnetic moments of 3d metal constituents in the sub-surface region of in situ cleaned fcc-structured Al0.3-CrFeCoNi compared to their bulk values. Extended to nanostructured versions of multicomponent alloys, such studies would bring new insights related to effects of high entropy mixing on low dimensions.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4061
Author(s):  
Yongtao Li ◽  
Liqing Liu ◽  
Dehao Wang ◽  
Hongguang Zhang ◽  
Xuemin He ◽  
...  

BiFeO3 is considered as a single phase multiferroic. However, its magnetism is very weak. We study the magnetic properties of BiFeO3 by Cu and (Cu, Zn). Polycrystalline samples Bi(Fe0.95Cu0.05)O3 and BiFe0.95(Zn0.025Cu0.025)O3 are prepared by the sol-gel method. The magnetic properties of BiFe0.95(Zn0.025Cu0.025)O3 are greater than that of BiFeO3 and Bi(Fe0.95Cu0.05)O3. The analyses of X-ray absorption fine structure data show that the doped Cu atoms well occupy the sites of the Fe atoms. X-ray absorption near edge spectra data confirm that the valence state of Fe ions does not change. Cu and Zn metal ion co-doping has no impact on the local structure of the Fe and Bi atoms. The modification of magnetism by doping Zn can be understood by the view of the occupation site of non-magnetically active Zn2+.


2020 ◽  
Vol 10 (03) ◽  
pp. 2050003
Author(s):  
M. R. Hassan ◽  
M. T. Islam ◽  
M. N. I. Khan

In this research, influence of adding Li2CO3 (at 0%, 2%, 4%, 6%) on electrical and magnetic properties of [Formula: see text][Formula: see text]Fe2O4 (with 60% Ni and 40% Mg) ferrite has been studied. The samples are prepared by solid state reaction method and sintered at 1300∘C for 6[Formula: see text]h. X-ray diffraction (XRD) patterns show the samples belong to single-phase cubic structure without any impurity phase. The magnetic properties (saturation magnetization and coercivity) of the samples have been investigated by VSM and found that the higher concentration of Li2CO3 reduces the hysteresis loss. DC resistivity increases with Li2CO3 contents whereas it decreases initially and then becomes constant at lower value with temperature which indicates that the studied samples are semiconductor. The dielectric dispersion occurs at a low-frequency regime and the loss peaks are formed in a higher frequency regime, which are due to the presence of resonance between applied frequency and hopping frequency of charge carriers. Notably, the loss peaks are shifted to the lower frequency with Li2CO3 additions.


2010 ◽  
Vol 322 (21) ◽  
pp. 3396-3400 ◽  
Author(s):  
Jianjun Li ◽  
Hongming Yuan ◽  
Guodong Li ◽  
Yanju Liu ◽  
Jinsong Leng

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