scholarly journals Decoupling electrocaloric effect from Joule heating in a solid state cooling device

2011 ◽  
Vol 99 (23) ◽  
pp. 232908 ◽  
Author(s):  
M. Quintero ◽  
L. Ghivelder ◽  
F. Gomez-Marlasca ◽  
F. Parisi
2020 ◽  
Vol 67 (4) ◽  
pp. 1769-1775
Author(s):  
Sankar Prasad Bag ◽  
Xu Hou ◽  
Jingtong Zhang ◽  
Shuanghao Wu ◽  
Jie Wang

2020 ◽  
Vol 8 (33) ◽  
pp. 16814-16830
Author(s):  
Hailong Hu ◽  
Fan Zhang ◽  
Shibin Luo ◽  
Jianling Yue ◽  
Chun-Hui Wang

Ferroelectric polymer nanocomposites demonstrate improved adiabatic change of temperature and isothermal change of entropy and markedly enhanced heating–cooling efficiency.


2022 ◽  
Vol 13 (1) ◽  
Author(s):  
Shixian Zhang ◽  
Quanling Yang ◽  
Chenjian Li ◽  
Yuheng Fu ◽  
Huaqing Zhang ◽  
...  

AbstractAlthough the elastocaloric effect was found in natural rubber as early as 160 years ago, commercial elastocaloric refrigeration based on polymer elastomers has stagnated owing to their deficient elastocaloric effects and large extension ratios. Herein, we demonstrate that polymer elastomers with uniform molecular chain-lengths exhibit enormous elastocaloric effects through reversible conformational changes. An adiabatic temperature change of −15.3 K and an isothermal entropy change of 145 J kg−1 K−1, obtained from poly(styrene-b-ethylene-co-butylene-b-styrene) near room temperature, exceed those of previously reported elastocaloric polymers. A rotary-motion cooling device is tailored to high-strains characteristics of rubbers, which effectively discharges the cooling energy of polymer elastomers. Our work provides a strategy for the enhancement of elastocaloric effects and could promote the commercialization of solid-state cooling devices based on polymer elastomers.


2019 ◽  
Vol 7 (45) ◽  
pp. 14109-14115 ◽  
Author(s):  
Biaolin Peng ◽  
Jintao Jiang ◽  
Silin Tang ◽  
Miaomiao Zhang ◽  
Laijun Liu ◽  
...  

The electrocaloric (EC) effect in ferroelectric/antiferroelectric thin films has been widely investigated due to its potential applications in solid state cooling devices.


2021 ◽  
Author(s):  
Jarad Mason ◽  
Jinyoung Seo ◽  
Ryan McGillicuddy ◽  
Adam Slavney ◽  
Selena Zhang ◽  
...  

Abstract Nearly 4,400 TWh of electricity—20% of the total consumed in the world—is used each year by refrigerators, air conditioners, and heat pumps for cooling. In addition to the 2.3 Gt of carbon dioxide emitted during the generation of this electricity, the vapor-compression-based devices that provided the bulk of this cooling emitted fluorocarbon refrigerants with a global warming potential equivalent to 1.5 Gt of carbon dioxide into the atmosphere. With population and economic growth expected to dramatically increase over the next several decades, the development of alternative cooling technologies with improved efficiency and reduced emissions will be critical to meeting global cooling needs in a more sustainable fashion. Barocaloric materials, which undergo thermal changes in response to applied hydrostatic pressure, offer the potential for solid-state cooling with high energy efficiency and zero direct emissions, as well as faster start-up times, quieter operation, greater amenability to miniaturization, and better recyclability than conventional vapor-compression systems. Efficient barocaloric cooling requires materials that undergo reversible phase transitions with large entropy changes, high sensitivity to hydrostatic pressure, and minimal hysteresis, the combination of which has been challenging to achieve in existing barocaloric materials. Here, we report a new mechanism for achieving colossal barocaloric effects near ambient temperature that exploits the large volume and conformational entropy changes of hydrocarbon chain-melting transitions within two-dimensional metal–halide perovskites. Significantly, we show how the confined nature of these order–disorder phase transitions and the synthetic tunability of layered perovskites can be leveraged to reduce phase transition hysteresis through careful control over the inorganic–organic interface. The combination of ultralow hysteresis (< 1.5 K) and high barocaloric coefficients (> 20 K/kbar) leads to large reversible isothermal entropy changes (> 200 J/kg•K) at record-low pressures (< 300 bar). We anticipate that these results will help facilitate the development of barocaloric cooling technologies and further inspire new materials and mechanisms for efficient solid-state cooling.


2012 ◽  
Vol 100 (24) ◽  
pp. 242901 ◽  
Author(s):  
Yanbing Jia ◽  
Y. Sungtaek Ju

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