Heavy atom nitroxyl radicals. VI. The electronic spectrum of jet-cooled H2PO, the prototypical phosphoryl free radical

2011 ◽  
Vol 135 (21) ◽  
pp. 214307 ◽  
Author(s):  
Mohammed A. Gharaibeh ◽  
Dennis J. Clouthier ◽  
Riccardo Tarroni
Keyword(s):  
Free Radical ◽  
Electronic Spectrum ◽  
Heavy Atom ◽  
Nitroxyl Radicals

Heavy atom nitroxyl radicals. V. An experimental andab initiostudy of the previously unknown H2PS free radical

2011 ◽  
Vol 135 (21) ◽  
pp. 214306 ◽  
Author(s):  
Robert A. Grimminger ◽  
Dennis J. Clouthier ◽  
Riccardo Tarroni
Keyword(s):  
Free Radical ◽  
Heavy Atom ◽  
Nitroxyl Radicals

Heavy atom nitroxyl radicals. II: Spectroscopic detection of H2As=O, the prototypical arsenyl free radical

2009 ◽  
Vol 131 (11) ◽  
pp. 114311 ◽  
Author(s):  
Sheng-Gui He ◽  
Fumie X. Sunahori ◽  
Jie Yang ◽  
Dennis J. Clouthier
Keyword(s):  
Free Radical ◽  
Heavy Atom ◽  
Nitroxyl Radicals

Phosphorus hyperfine structure in the electronic spectrum of the HPCl free radical

2004 ◽  
Vol 121 (3) ◽  
pp. 1405-1411 ◽  
Author(s):  
Brandon S. Tackett ◽  
Dennis J. Clouthier ◽  
Allan G. Adam ◽  
Scott A. Shepard
Keyword(s):  
Free Radical ◽  
Hyperfine Structure ◽  
Electronic Spectrum

scholarly journals Sodium nitrite and ascorbic acid: a metal-free combination that controls the free-radical polymerization of tert-butyl methacrylate in water

e-Polymers ◽  
2002 ◽  
Vol 2 (1) ◽  
Author(s):  
Christophe Detrembleur ◽  
Ange Mouithys-Mickalad ◽  
Philippe Teyssié ◽  
Robert Jérôme
Keyword(s):  
Nitric Oxide ◽  
Ascorbic Acid ◽  
Free Radical ◽  
Radical Polymerization ◽  
Sodium Nitrite ◽  
Free Radical Polymerization ◽  
Nitroxyl Radicals ◽  
Butyl Methacrylate ◽  
Metal Free ◽  
Tert Butyl

AbstractA mixture of sodium nitrite and ascorbic acid is able to control the radical polymerization of tert-butyl methacrylate (tBMA) in water at 80°C. Indeed, sodium nitrite is reduced by the ascorbic acid, and the nitric oxide (NO) which is formed insitu is nothing but a promoter of nitroxyl radicals. The radical polymerization of tBMA is thus basically controlled by a nitroxide-mediated process.

Ab initio CI study of the electronic spectrum of the interstellar free radical CP

1994 ◽  
Vol 185 (1) ◽  
pp. 39-45 ◽  
Author(s):  
Jian-ping Gu ◽  
Robert J. Buenker ◽  
Gerhard Hirsch
Keyword(s):  
Free Radical ◽  
Ab Initio ◽  
Electronic Spectrum
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