Crystal structure evolution and local symmetry of perovskite solid solution Ba[(Fe1/2Nb1/2)1−xTix]O3 investigated by Raman spectra

2011 ◽  
Vol 110 (6) ◽  
pp. 064113 ◽  
Author(s):  
Wei Zhang ◽  
Zhuo Wang ◽  
Xiang Ming Chen
2016 ◽  
Vol 45 (3) ◽  
pp. 1007-1015 ◽  
Author(s):  
Yufei Xia ◽  
Jian Chen ◽  
Yan-gai Liu ◽  
Maxim S. Molokeev ◽  
Ming Guan ◽  
...  

The substitution of La3+ by Ca2+ in a series of phosphors led to a crystal structure variation and the emitted color changing from green to blue.


Author(s):  
Jennifer H. Stansby ◽  
Neeraj Sharma ◽  
Maxim Avdeev ◽  
Helen E. A. Brand ◽  
Bernt Johannessen ◽  
...  

1983 ◽  
Vol 213 (2) ◽  
pp. 503-506 ◽  
Author(s):  
G Musci ◽  
A Desideri ◽  
L Morpurgo ◽  
A Garnier-Suillerot ◽  
L Tosi

Resonance-Raman spectra of Japanese-lacquer-tree (Rhus vernicifera) laccase, type-2-copper-depleted laccase and the latter form treated with H2O2 were measured in liquid and frozen solution, on excitation into the 600 nm absorption band. Significant changes in intensity and/or frequency of the bands lying in the 370-430 cm-1 region were observed on freezing, indicating local structural rearrangements taking place at the blue copper site. These findings corroborate previous suggestions based on e.p.r. measurements and redox data [Morpurgo, Calabrese, Desideri & Rotilio (1981) Biochem. J. 193, 639-642]. They show the strong dependence of the physical properties of blue copper centres on local symmetry. Some conclusions on the origin of the Raman bands are also drawn.


2021 ◽  
pp. 153189
Author(s):  
Pham Van Mao ◽  
Tatsumi Arima ◽  
Yaohiro Inagaki ◽  
Kazuya Idemitsu ◽  
Daisuke Akiyama ◽  
...  

1984 ◽  
Vol 39 (4) ◽  
pp. 357-361 ◽  
Author(s):  
Robert Becker ◽  
Wolfgang Brockner ◽  
Herbert Schäfer

Pb2P2Se6 crystallizes in the monoclinic system, space group Pn (No. 13) with the lattice constantsa = 974.2 (4) pm. b = 766.2 (3) pm. c = 689.8 (3) pm, β=91.44(5)°.The title compound is isotypic to the homologous Pb2P2S6. In the structure there are discrete P2Se4-6 anions.Far infrared, infrared and Raman spectra of this compound have been recorded. The observed frequencies are assigned on the basis of P2Se4-6 units with C2h symmetry in the crystal. DTA-data have been determined and interpreted.


2002 ◽  
Vol 165 (2) ◽  
pp. 324-333 ◽  
Author(s):  
Olivier Cousin ◽  
Marielle Huve ◽  
Pascal Roussel ◽  
Olivier Perez ◽  
Hugo Steinfink

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