Publisher's Note: “Time-resolved photoelectron imaging of S2 → S1 internal conversion in benzene and toluene” [J. Chem. Phys. 134, 184313 (2011)]

2011 ◽  
Vol 135 (9) ◽  
pp. 099901
Author(s):  
Yoshi-Ichi Suzuki ◽  
Takuya Horio ◽  
Takao Fuji ◽  
Toshinori Suzuki
2012 ◽  
Vol 28 (11) ◽  
pp. 2543-2548
Author(s):  
GHAZAl Ahmed-Yousif ◽  
◽  
QIU Xue-Jun ◽  
QIN Chao-Chao ◽  
LONG Jin-You ◽  
...  

2012 ◽  
Vol 28 (12) ◽  
pp. 2761-2766
Author(s):  
DING Zhong-Hua ◽  
◽  
◽  
QIU Xue-Jun ◽  
XU Yan-Qi ◽  
...  

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
James N. Bull ◽  
Cate S. Anstöter ◽  
Jan R. R. Verlet

AbstractNon-valence states in neutral molecules (Rydberg states) have well-established roles and importance in photochemistry, however, considerably less is known about the role of non-valence states in photo-induced processes in anions. Here, femtosecond time-resolved photoelectron imaging is used to show that photoexcitation of the S1(ππ*) state of the methyl ester of deprotonated para-coumaric acid – a model chromophore for photoactive yellow protein (PYP) – leads to a bifurcation of the excited state wavepacket. One part remains on the S1(ππ*) state forming a twisted intermediate, whilst a second part leads to the formation of a non-valence (dipole-bound) state. Both populations eventually decay independently by vibrational autodetachment. Valence-to-non-valence internal conversion has hitherto not been observed in the intramolecular photophysics of an isolated anion, raising questions into how common such processes might be, given that many anionic chromophores have bright valence states near the detachment threshold.


2010 ◽  
Vol 132 (17) ◽  
pp. 174302 ◽  
Author(s):  
Yoshi-Ichi Suzuki ◽  
Takao Fuji ◽  
Takuya Horio ◽  
Toshinori Suzuki

2013 ◽  
Vol 21 (14) ◽  
pp. 16639 ◽  
Author(s):  
Yuzhu Liu ◽  
Thomas Gerber ◽  
Yaroslav Sych ◽  
Peter Radi ◽  
Gregor Knopp

2010 ◽  
Vol 18 (6) ◽  
pp. 5791 ◽  
Author(s):  
Yuzhu Liu ◽  
Bifeng Tang ◽  
Huan Shen ◽  
Song Zhang ◽  
Bing Zhang

2014 ◽  
Vol 22 (8) ◽  
pp. 9115
Author(s):  
Yuzhu Liu ◽  
Thomas Gerber ◽  
Yaroslav Sych ◽  
Peter Radi ◽  
Gregor Knopp

2011 ◽  
Vol 134 (18) ◽  
pp. 184313 ◽  
Author(s):  
Yoshi-Ichi Suzuki ◽  
Takuya Horio ◽  
Takao Fuji ◽  
Toshinori Suzuki

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