Temperature and methanol concentration dependences of direct methanol fuel cell performance measured by single cell having reference electrode

2011 ◽  
Vol 3 (4) ◽  
pp. 043107 ◽  
Author(s):  
Minoru Umeda ◽  
Kazuya Sayama ◽  
Mitsuhiro Inoue
2009 ◽  
Vol 194 (2) ◽  
pp. 674-682 ◽  
Author(s):  
Zhaoxia Hu ◽  
Takahiro Ogou ◽  
Makoto Yoshino ◽  
Otoo Yamada ◽  
Hidetoshi Kita ◽  
...  

2013 ◽  
Vol 10 (5) ◽  
Author(s):  
K. Scott ◽  
S. Pilditch ◽  
M. Mamlouk

A steady-state, isothermal, one-dimensional model of a direct methanol proton exchange membrane fuel cell (PEMFC), with a polybenzimidazole (PBI) membrane, was developed. The electrode kinetics were represented by the Butler–Volmer equation, mass transport was described by the multicomponent Stefan–Maxwell equations and Darcy's law, and the ionic and electronic resistances described by Ohm's law. The model incorporated the effects of temperature and pressure on the open circuit potential, the exchange current density, and diffusion coefficients, together with the effect of water transport across the membrane on the conductivity of the PBI membrane. The influence of methanol crossover on the cathode polarization is included in the model. The polarization curves predicted by the model were validated against experimental data for a direct methanol fuel cell (DMFC) operating in the temperature range of 125–175 °C. There was good agreement between experimental and model data for the effect of temperature and oxygen/air pressure on cell performance. The fuel cell performance was relatively poor, at only 16 mW cm−2 peak power density using low concentrations of methanol in the vapor phase.


RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47129-47135 ◽  
Author(s):  
Yituo Wang ◽  
Guimei Han ◽  
Zhe Tian ◽  
Meng Wang ◽  
Jianling Li ◽  
...  

Bentonite (BOT) has excellent hygroscopicity and large specific surface, so it is chosen as a dopant of Nafion® membranes in this paper.


2011 ◽  
Vol 347-353 ◽  
pp. 3275-3280 ◽  
Author(s):  
Xian Qi Cao ◽  
Ji Tian Han ◽  
Ze Ting Yu ◽  
Pei Pei Chen

In this work, the effect of the current-collector structure on the performance of a passive direct methanol fuel cell (DMFC) was investigated. Parallel current-collector (PACC) and other two kinds of perforated current collectors (PECC) were designed, fabricated and tested. The studies were conducted in a passive DMFC with active membrane area of 9 cm2, working at ambient temperature and pressure. Two kinds of methanol solution of 2 M and 4 M were used. Results showed that the PACC as anode current-collector has a positive effect on cell voltage and power. For the cathode current-collector structure, the methanol concentration of 2 M for PECC-2 (higher open ratio 50.27 %) increased performance of DMFC. But the methanol concentration of 4 M led to an enhancement of fuel cell performance that used PACC or PECC-2 as cathode current-collector.


2014 ◽  
Vol 245 ◽  
pp. 37-47 ◽  
Author(s):  
Prabhuram Joghee ◽  
Svitlana Pylypenko ◽  
Kevin Wood ◽  
April Corpuz ◽  
Guido Bender ◽  
...  

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