Crystallization process of amorphous GaSb films studied by Raman spectroscopy

1995 ◽  
Vol 77 (8) ◽  
pp. 4044-4048 ◽  
Author(s):  
J. H. Dias da Silva ◽  
S. W. da Silva ◽  
J. C. Galzerani
Carbon ◽  
2016 ◽  
Vol 101 ◽  
pp. 22-27 ◽  
Author(s):  
Pengfei Zhai ◽  
Jie Liu ◽  
Jian Zeng ◽  
Jinglai Duan ◽  
Lijun Xu ◽  
...  

2009 ◽  
Vol 156-158 ◽  
pp. 41-48 ◽  
Author(s):  
M. Holla ◽  
Tzanimir Arguirov ◽  
Winfried Seifert ◽  
Martin Kittler

We report on the optical and mechanical properties of Si3N4 inclusions, formed in the upper part of mc-Si blocks during the crystallization process. Those inclusions usually appear as crystalline hexagonal tubes or rods. Here we show that in many cases the Si3N4 inclusions contain crystalline Si in their core. The presence of the Si phase in the centre was proven by means of cathodoluminescence spectroscopy and imaging, electron beam induced current measurements and Raman spectroscopy. The crystalline Si3N4 phase was identified as β-Si3N4. Residual stress was revealed at the particles. While the stress is compressive in the Si material surrounding the Si3N4 particles tensile stress is found in the Si core. We assume that the stress is formed during cool down of the Si block and is a consequence of the larger thermal expansion coefficient of Si in comparison to that of β-Si3N4. Iron assisted nitridation of Si at temperatures below 1400 °C is considered a possible mechanism of Si3N4 formation.


2006 ◽  
Vol 910 ◽  
Author(s):  
Rosari Saleh ◽  
Norbert H Nickel

AbstractA series of boron doped polycrystalline silicon were produced using step-by-step laser crystallization process from amorphous silicon. The influence of doping concentrations on laser- induced dehydrogenation and crystallization of amorphous silicon and on hydrogen bonding have been investigated employing Raman spectroscopy and hydrogen effusion measurements. From hydrogen effusion spectra the hydrogen chemical potential is determined as a function of hydrogen concentration, which can be related to the hydrogen density-of-states distribution. The results from hydrogen effusion are consistent with the results obtained from Raman spectroscopy.


2008 ◽  
Vol 22 (11-12) ◽  
pp. 644-652 ◽  
Author(s):  
Hannu Alatalo ◽  
Jarno Kohonen ◽  
Haiyan Qu ◽  
Henry Hatakka ◽  
Satu-Pia Reinikainen ◽  
...  

1987 ◽  
Vol 111 ◽  
Author(s):  
Prabir K. Dutta ◽  
M. Puri ◽  
D. C. Shieh

AbstractRaman spectroscopy of the solution, solid and gel phases present during crystallization of zeolite X was investigated. The vibrational data indicate that an amorphous aluminosilicate solid, composed primarily of four membered aluminosilicate rings is in contact with monomeric silicate ions during the prenucleation stages of the zeolite formation. No intermediate building blocks specific to zeolite X could be discerned from the vibrational spectra. The influence of a series of monovalent cations on the crystallization process was also examined, and a model of zeolite formation has been proposed.


1995 ◽  
Vol 397 ◽  
Author(s):  
C. García ◽  
A.C. Prieto ◽  
J. Jiménez ◽  
J. Siegel ◽  
J. Solís ◽  
...  

ABSTRACTStructural transformations induced in amorphous Ge films by picosecond laser pulses are studied by means of Raman spectroscopy and their dependence on parameters like the pulse fluence or the thermal conductivity of the substrate are analyzed. A correlation length model is used for studying the crystallization process, while the average bond angle distortion is used for determining the state of relaxation of the amorphous phase. Silicon and glass substrates are compared.


2018 ◽  
Vol 5 (8) ◽  
pp. 2031-2037 ◽  
Author(s):  
Xiaohua Ju ◽  
Fuping Tian ◽  
Yanli Wang ◽  
Fengtao Fan ◽  
Zhaochi Feng ◽  
...  

A novel two-step crystallization process of Fe-ZSM-35 zeolite was designed, and analyzed by UV resonance Raman spectroscopy.


1983 ◽  
Vol 44 (11) ◽  
pp. 313-318 ◽  
Author(s):  
Masaaki Takashige ◽  
Terutaro Nakamura ◽  
Yutaka Aikawa

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