Anomalous Curie temperature behavior of A-site Gd-doped BaTiO3 ceramics: The influence of strain

2011 ◽  
Vol 98 (9) ◽  
pp. 092907 ◽  
Author(s):  
Liubin Ben ◽  
Derek C. Sinclair
1993 ◽  
Vol 152 (2-3) ◽  
pp. 212-218 ◽  
Author(s):  
Tae-Hwan Noh ◽  
Akihisa Inoue ◽  
Hiroyasu Fujimori ◽  
Tsuyoshi Masumoto

2017 ◽  
Vol 43 (14) ◽  
pp. 10683-10690 ◽  
Author(s):  
Shujuan Liu ◽  
Lixue Zhang ◽  
Jiping Wang ◽  
Yingying Zhao ◽  
Xuan Wang

2015 ◽  
Vol 54 (7S1) ◽  
pp. 07HB04 ◽  
Author(s):  
Shota Fujimoto ◽  
Takao Namihira ◽  
Kazuki Iwata ◽  
Makiko Kobayashi

2013 ◽  
Vol 566 ◽  
pp. 72-75 ◽  
Author(s):  
Akihiro Mitani ◽  
Yoshinari Oba

Recently, high performance lead-free piezoelectric materials are strongly demanded for environmental issues. (K0.5Na0.5)NbO3 (KNN) has been attracting interest as lead-free piezoelectric ceramics because of its high Curie temperature and excellent piezoelectric properties. In this study, we investigated effects of Li addition on piezoelectric properties of (Li,Na,K)(Nb+Ta)O3+CuO,BaTiO3 . We found that optimum Li ratio of A site and B site on the perovskite structure increases relative density and .


2001 ◽  
Vol 40 (Part 1, No. 11) ◽  
pp. 6501-6505 ◽  
Author(s):  
Haixue Yan ◽  
Chengen Li ◽  
Jiaguang Zhou ◽  
Weimin Zhu ◽  
Lianxin He ◽  
...  

Crystals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 434
Author(s):  
Lan Xu ◽  
Zujian Wang ◽  
Bin Su ◽  
Chenxi Wang ◽  
Xiaoming Yang ◽  
...  

Lanthanide doping is widely employed to tune structural change temperature and electrical properties in ABO3-type perovskite ferroelectric materials. However, the reason that A-site lanthanide doping leads to the decrease of the Curie temperature is still not clear. Based on the reported Curie temperature of lanthanides (Ln) doped in two classic ferroelectrics PbTiO3 and BaTiO3 with A2+B4+O3-type perovskite structure, we discussed the relationship between the decrease rate of Curie temperature (ΔTC) and the bond strength variance of A-site cation (σ). For Nd ion doped Pb(Mg1/3Nb2/3)O3-PbTiO3 (Nd-PMNT) ferroelectric crystal as an example, the internal factors of the dramatic decline of the Curie temperature induced by A-site Nd doping were investigated under a systematic study. The strong covalent bonds of Ln-O play an important role in A-site Ln composition-induced structural change from ferroelectric to paraelectric phase, and it is responsible for the significant decrease in the Curie temperature. It is proposed that the cells become cubic around the Ln ions due to the strong covalent energy of Ln-O bonding in A-site Ln doped A2+B4+O3 perovskite ferroelectrics.


2008 ◽  
Vol 388 ◽  
pp. 221-224
Author(s):  
Teppei Kubota ◽  
Nobuhiko Tanaka ◽  
Keisuke Kageyama ◽  
Hiroshi Takagi ◽  
Yukio Sakabe

The electrooptic material of transparent (Sr,Ba)Nb2O6 (SBN) ceramics was prepared using the conventional solid-phase reaction process with no special techniques such as hot-pressing or hot isostatic pressing. The SBN ceramics were made transparent by substituting a small amount of Zn2+ ion for the B site (Nb5+ ion site). The Curie temperature was increased by substituting a small amount of Na+ ion for the A site (Sr2+ or Ba2+ site). Furthermore, the orientation of the SBN structure by the template grain growth (TGG) method improved the electrooptic properties of the ceramics.


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