Carbon nanotube chains in a shape memory polymer/carbon black composite: To significantly reduce the electrical resistivity

2011 ◽  
Vol 98 (7) ◽  
pp. 074102 ◽  
Author(s):  
Kai Yu ◽  
Zhichun Zhang ◽  
Yanju Liu ◽  
Jinsong Leng
Keyword(s):  
Electrical Resistivity ◽  
Carbon Nanotube ◽  
Carbon Black ◽  
Shape Memory ◽  
Shape Memory Polymer

Investigate of Electrical Conductivity of Shape-Memory Polymer Filled with Carbon Black

2008 ◽  
Vol 47-50 ◽  
pp. 714-717 ◽  
Author(s):  
Xin Lan ◽  
Jin Song Leng ◽  
Yan Ju Liu ◽  
Shan Yi Du
Keyword(s):  
Electrical Conductivity ◽  
Carbon Black ◽  
Shape Memory ◽  
Shape Recovery ◽  
Volume Fraction ◽  
Shape Memory Polymer ◽  
Recovery Process ◽  
Thermomechanical Properties ◽  
Electrically Conductive ◽  
New System

A new system of thermoset styrene-based shape-memory polymer (SMP) filled with carbon black (CB) is investigated. To realize the electroactive stimuli of SMP, the electrical conductivity of SMP filled with various amounts of CB is characterized. The percolation threshold of electrically conductive SMP filled with CB is about 3% (volume fraction of CB), which is much lower than many other electrically conductive polymers. When applying a voltage of 30V, the shape recovery process of SMP/CB(10 vol%) can be realized in about 100s. In addition, the thermomechanical properties are also characterized by differential scanning calorimetery (DSC).

Interphase influences on the mechanical behavior of carbon nanotube–shape memory polymer nanocomposites: A micromechanical approach

2018 ◽  
Vol 30 (3) ◽  
pp. 463-478 ◽  
Author(s):  
MK Hassanzadeh-Aghdam ◽  
MJ Mahmoodi ◽  
R Ansari ◽  
A Darvizeh
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Shape Memory ◽  
Polymer Nanocomposites ◽  
Elastic Moduli ◽  
Volume Fraction ◽  
Shape Memory Polymer ◽  
Micromechanical Model ◽  
Elastic Behavior ◽  
Interphase Region

The effects of interphase characteristics on the elastic behavior of randomly dispersed carbon nanotube–reinforced shape memory polymer nanocomposites are investigated using a three-dimensional unit cell–based micromechanical method. The interphase region is formed due to non-bonded van der Waals interaction between a carbon nanotube and a shape memory polymer. The influences of temperature, diameter, volume fraction, and arrangement type of carbon nanotubes within the matrix as well as two interphase factors, including adhesion exponent and thickness on the carbon nanotube/shape memory polymer nanocomposite’s longitudinal and transverse elastic moduli, are explored extensively. Moreover, the results are presented for the shape memory polymer nanocomposites containing randomly oriented carbon nanotubes. The obtained results clearly demonstrate that the interphase region plays a crucial role in the modeling of the carbon nanotube/shape memory polymer nanocomposite’s elastic moduli. It is observed that the nanocomposite’s elastic moduli remarkably increase with increasing interphase thickness or decreasing adhesion exponent. It is found that when the interphase is considered in the micromechanical simulation, the shape memory polymer nanocomposite’s elastic moduli non-linearly increase as the carbon nanotube diameter decreases. The predictions of the present micromechanical model are compared with those of other analytical methods and available experiments.

scholarly journals Determination of Shape Fixity and Shape Recovery Rate of Carbon Nanotube-filled Shape Memory Polymer Nanocomposites

2012 ◽  
Vol 41 ◽  
pp. 1641-1646 ◽  
Author(s):  
Shahrul Azam Abdullah ◽  
Aidah Jumahat ◽  
Nik Rosli Abdullah ◽  
Lars Frormann
Keyword(s):  
Carbon Nanotube ◽  
Shape Memory ◽  
Polymer Nanocomposites ◽  
Recovery Rate ◽  
Shape Recovery ◽  
Shape Memory Polymer ◽  
Shape Fixity

3D printing of shape memory polymer (SMP)/carbon black (CB) nanocomposites with electro-responsive toughness enhancement

2018 ◽  
Vol 5 (6) ◽  
pp. 065704 ◽  
Author(s):  
Carlos A Garcia Rosales ◽  
Mario F Garcia Duarte ◽  
Hoejin Kim ◽  
Luis Chavez ◽  
Deidra Hodges ◽  
...  
Keyword(s):  
3D Printing ◽  
Carbon Black ◽  
Shape Memory ◽  
Shape Memory Polymer ◽  
Toughness Enhancement

scholarly journals Functionally graded carbon nanotube and nafion/silica nanofibre for electrical actuation of carbon fibre reinforced shape memory polymer

2016 ◽  
Vol 45 (2) ◽  
pp. 93-98 ◽  
Author(s):  
Haibao Lu ◽  
Yongtao Yao ◽  
Jinying  Yin ◽  
Long Lin
Keyword(s):  
Carbon Nanotube ◽  
Carboxylic Acid ◽  
Carbon Fibre ◽  
Shape Memory ◽  
Shape Recovery ◽  
Shape Memory Polymer ◽  
Functionally Graded ◽  
Content Type ◽  
Electrical Actuation ◽  
Electrical Voltage

Purpose – This paper aims to study the synergistic effect of self-assembled carboxylic acid-functionalised carbon nanotube (CNT) and nafion/silica nanofibre nanopaper on the electro-activated shape memory effect (SME) and shape recovery behaviour of shape memory polymer (SMP) nanocomposite. Design/methodology/approach – Carboxylic acid-functionalised CNT and nafion/silica nanofibre are first self-assembled onto carbon fibre by means of deposition and electrospinning approaches, respectively, to form functionally graded nanopaper. The combination of carbon fibre and CNT is introduced to enable the actuation of the SME in SMP by means of Joule heating at a low electric voltage of 3.0-5.0 V. Findings – Nafion/silica nanofibre is used to improve the shape recovery behaviour and performance of the SMP for enhanced heat transfer and electrical actuation effectiveness. Low electrical voltage actuation and high electrical actuation effectiveness of 32.5 per cent in SMP has been achieved. Research limitations/implications – A simple way for fabricating electro-activated SMP nanocomposites has been developed by using functionally graded CNT and nafion/silica nanofibre nanopaper. Originality/value – The outcome of this study will help to fabricate the SMP composite with high electrical actuation effectiveness under low electrical voltage actuation.

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