The glass transition behaviors of low-density amorphous ice films with different thicknesses

2010 ◽  
Vol 133 (20) ◽  
pp. 204504 ◽  
Author(s):  
Cheng He ◽  
Wenxue Zhang ◽  
Yu Li
2013 ◽  
Vol 15 (23) ◽  
pp. 9308 ◽  
Author(s):  
Florian Löw ◽  
Katrin Amann-Winkel ◽  
Thomas Loerting ◽  
Franz Fujara ◽  
Burkhard Geil

2010 ◽  
Vol 24 (17) ◽  
pp. 1915-1921 ◽  
Author(s):  
H. YURTSEVEN ◽  
M. KURT

We analyze the heat capacity CP for low and high-density amorphous ice below the transition temperature (TC ≈ 140 K ) using a power-law formula. The renormalized critical exponent αR is extracted from the observed CP data, which describes similar critical behavior for both low and high-density amorphous ice below TC. Our analysis can also describe a glass transition in the low-density amorphous ice which is made from the high-density amorphous ice at 124 K, as observed experimentally.


Author(s):  
Daniel Mariedahl ◽  
Fivos Perakis ◽  
Alexander Späh ◽  
Harshad Pathak ◽  
Kyung Hwan Kim ◽  
...  

Here we report about the structural evolution during the conversion from high-density amorphous ices at ambient pressure to the low-density state. Using high-energy X-ray diffraction, we have monitored the transformation by following in reciprocal space the structure factor S OO ( Q ) and derived in real space the pair distribution function g OO ( r ). Heating equilibrated high-density amorphous ice (eHDA) at a fast rate (4 K min –1 ), the transition to the low-density form occurs very rapidly, while domains of both high- and low-density coexist. On the other hand, the transition in the case of unannealed HDA (uHDA) and very-high-density amorphous ice is more complex and of continuous nature. The direct comparison of eHDA and uHDA indicates that the molecular structure of uHDA contains a larger amount of tetrahedral motives. The different crystallization behaviour of the derived low-density amorphous states is interpreted as emanating from increased tetrahedral coordination present in uHDA. This article is part of the theme issue ‘The physics and chemistry of ice: scaffolding across scales, from the viability of life to the formation of planets'.


2019 ◽  
Vol 123 (29) ◽  
pp. 17855-17863 ◽  
Author(s):  
Rebecca S. Thompson ◽  
Michelle R. Brann ◽  
S. J. Sibener

2000 ◽  
Vol 61 (1) ◽  
pp. 28-31 ◽  
Author(s):  
László Pusztai
Keyword(s):  

1989 ◽  
Vol 91 (11) ◽  
pp. 7187-7192 ◽  
Author(s):  
M. A. Floriano ◽  
Y. P. Handa ◽  
D. D. Klug ◽  
Edward Whalley

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