Effect of Shear Rate and Nanoclay Content on the Die Swell of Polypropylene Nanocomposites Extruded Under Capillary Flow

2010 ◽  
Author(s):  
Tripti Dixit ◽  
Vishal Das ◽  
Vineeta Nigam ◽  
A. K. Pandey ◽  
P. K. Giri ◽  
...  
Keyword(s):  
Shear Rate ◽  
Capillary Flow ◽  
Die Swell ◽  
Polypropylene Nanocomposites ◽  
Nanoclay Content

Capillary Rheometry of Carbon-Black-Filled Butadiene—Acrylonitrile Copolymers

1975 ◽  
Vol 48 (4) ◽  
pp. 615-622 ◽  
Author(s):  
N. Nakajima ◽  
E. A. Collins
Keyword(s):  
Shear Rate ◽  
Carbon Black ◽  
Tensile Stress ◽  
Capillary Flow ◽  
Complex Viscosity ◽  
Appreciable Effect ◽  
Stress Strain ◽  
Capillary Rheometry ◽  
Strain Behavior ◽  
Acrylonitrile Copolymers

Abstract Capillary rheometry of carbon-black-filled butadiene—acrylonitrile copolymers at 125°C was performed over a wide shear rate range. The data were corrected for pressure loss in the barrel and at the capillary entrance, and for the non-Newtonian velocity profile (Rabinowitsch correction). No appreciable effect of pressure on viscosity was observed. The die swell values were very small, 1.1–1.4. This fact and the shape of the plots of shear stress vs. shear rate imply the presence of a particulate structure, which is probably built by carbon black surrounded with bound rubber. Unlike the behavior of raw amorphous elastomers, the steady-shear viscosity, the dynamic complex viscosity, and the viscosity calculated from tensile stress-strain behavior were significantly different from each other. That is, the capillary flow data indicated an alteration of the structure towards strain softening, and the tensile stress-strain behavior showed strain hardening, indicating retention of the structure up to the yield point. In the dynamic measurement, being conducted at very small strain, the structure is least disturbed. With unfilled elastomers essentially the same deformational mechanism was believed to be responsible in these three measurements, because the results can be expressed by a single master curve.

Compaction and flow of potato starch and potato granules Compactación y flujo de almidón de patata y gránulos de patata

1997 ◽  
Vol 3 (5) ◽  
pp. 333-342 ◽  
Author(s):  
P.J. Halliday ◽  
A.C. Smith
Keyword(s):  
Shear Stress ◽  
Shear Rate ◽  
Wall Shear Stress ◽  
Water Content ◽  
Capillary Flow ◽  
Potato Starch ◽  
Slip Flow ◽  
Shear Stresses ◽  
Wall Shear ◽  
Water Contents

Potato starch and potato granules are materials that are often used in extrusion processes. It is important to quantify their rheology for modelling and prediction of process performance. The compaction behaviour of potato starch was examined at water contents of 4-18% wwb (wet weight basis) for pressures between 1 and 85 MPa. The Heckel deformation stress decreased as the water content increased up to 12% but became inaccurate at 18%. This decrease agreed qualitatively with other observations of the decrease in stiffness of starchy materials over this water content range. Potato granules were examined at water contents of 25-45% wwb and aspects of their rheo logical behaviour characterized using different approaches. A first approximation used the shear viscosity-shear rate power law which produced a law exponent for the resulting pastes (0.1-0.2). The classical Benbow equation was used to estimate yield and wall shear stresses in capillary flow. The latter indicates the presence of slip which was examined more fully as a function of wall shear stress. The Mooney technique was used together with a variation of the method where the shear rate for each die was subtracted from that for a non-slip flow, which was approximated using rough dies. A critical wall shear stress for slip was found to be 0.05-0.1 MPa, making it consistent with published results for other materials.

Experimental Research on the Viscosity of Polymer Melts Filling through Micro Channels

2011 ◽  
Vol 314-316 ◽  
pp. 1346-1349
Author(s):  
Bin Xu ◽  
Yu Bin Lu ◽  
Guang Ming Li ◽  
Song Xue
Keyword(s):  
Shear Rate ◽  
Flow Model ◽  
Capillary Flow ◽  
Polymer Melt ◽  
Characteristic Size ◽  
Micro Channel ◽  
Test Results ◽  
Micro Channels ◽  
Rate Test ◽  
The Difference

Experimental observations indicate that the viscosity of polymer melt flowing through micro channel is altered with variation of characteristic size of micro channels. The explanation about the trend of various viscosity is inconsistent. In this paper, the micro channel dies of 1000μm ,500μm and 350μm diameter were developed and with several polymers, including PP , PS and HDPE, depending on the capillary flow model, the measurement experiments of polymer melt viscosity were investigated at various shear rate. Test results show that with micro-channel size decrease, the percentage reduction in viscosity increases and the difference of viscosities in different micro channels reduces with increasing shear rate.

End pressure effects of polypropylene composites reinforced with multi-walled carbon nanotubes in capillary flow

2019 ◽  
pp. 089270571987058
Author(s):  
Ji-Zhao Liang
Keyword(s):  
Carbon Nanotubes ◽  
Shear Rate ◽  
Pressure Drop ◽  
Test Temperature ◽  
Capillary Flow ◽  
Pressure Effects ◽  
Multi Walled Carbon Nanotubes ◽  
Apparent Shear Rate ◽  
Walled Carbon Nanotubes ◽  
Capillary Extrusion

The influence of the size and content of multi-walled carbon nanotubes (MWCNTs) on the end pressure effects of polypropylene (PP) composite melts during capillary extrusion flow was investigated, with the test temperature varying from 190°C to 230°C and apparent shear rate ranging from 50 s−1 to 3000 s−1. The results showed that the end pressure drop increased with increasing apparent shear rates, while decreased with increasing test temperature, and the sensitivity of the end pressure drop to apparent shear rate for the composites was higher than that for the unfilled PP. The end pressure drop increased with increasing weight fraction and the specific surface area of the MWCNTs. The end pressure drop increased almost linearly with increasing the aspect ratio of the MWCNTs. Moreover, the end pressure effect mechanisms of the composite melts during a capillary extrusion flow were discussed.

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