scholarly journals Thermodynamic properties and crystallization kinetics of glass‐forming undercooled liquid Au‐Pb‐Sb alloys

1990 ◽  
Vol 68 (9) ◽  
pp. 4494-4502 ◽  
Author(s):  
H. J. Fecht ◽  
J. H. Perepezko ◽  
M. C. Lee ◽  
W. L. Johnson
Metals ◽  
2016 ◽  
Vol 6 (9) ◽  
pp. 225 ◽  
Author(s):  
Xiaoliang Han ◽  
Yusheng Qin ◽  
Kai Qin ◽  
Xuelian Li ◽  
Shenghai Wang ◽  
...  

2014 ◽  
Vol 960-961 ◽  
pp. 161-164 ◽  
Author(s):  
Juan Mu ◽  
Hai Feng Zhang

Glass forming ability and crystallization kinetics of Al-Mg-Ni-La alloys have been investigated by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The maximum thickness achievable in glasses of Al76Mg11Ni8La5and Al69Mg18Ni8La5ribbons were 200 and 120 μm, respectively. The crystallization temperature and peak temperature indicated by DSC measurements displayed dependence on the heating rate during continuous heating, and were coincident with Lanoka’s relationship. The activation energies for the crystallization reactionExwere obtained from the Kissinger’s equation. The results show the Mg addition is beneficial to the thermal stability of the amorphous phase.


1998 ◽  
Vol 551 ◽  
Author(s):  
S.C. Glade ◽  
D.S. Lee ◽  
R. Wunderlich ◽  
W.L. Johnson

AbstractAn AC modulation calorimetry (ACMC) experiment was performed on two bulk metallic glass forming alloys, Ti34Zr11CU47Ni8 (VIT 101) and Zr57Nb5Ni12.6Al10Cu15.4(VIT 106) on the recent MSL-1 shuttle flight using the TEMPUS hardware. VIT 106 exhibited a maximum undercooling of 140 K in free radiative cooling, while VIT 101 exhibited a smaller undercooling of 50 K. Specific heat measurements were done in both the stable and undercooled liquid regions. These results will be combined with further ground-based measurements in an electrostatic levitator for modeling the nucleation kinetics of these alloys and for calculation of the free energies and entropies of the undercooled liquids in these systems.


2009 ◽  
Vol 24 (5) ◽  
pp. 1886-1895 ◽  
Author(s):  
Dmitri V. Louzguine-Luzgin ◽  
Guoqiang Xie ◽  
Song Li ◽  
Qingsheng Zhang ◽  
Wei Zhang ◽  
...  

The crystallization behavior of melt-spun ribbons and bulk samples of the Cu36Zr48Al8Ag8 glassy alloy on heating is presented here. The crystallization kinetics and structural changes in the Cu36Zr48Al8Ag8 glassy alloy were studied using x-ray diffraction, transmission electron microscopy, differential scanning, and isothermal calorimetry methods. A clear comparison is made of the differences in the crystallization kinetics of the melt-spun ribbons and the copper-mold-cast bulk rod samples. It was suggested that the kinetics of crystallization in the rod sample, at any given temperature, are somewhat different than in the ribbon samples, probably because of size and free volume effects. Differences in the crystallization behavior of this alloy with other Cu-Zr-Al-Ag alloys have also been discussed.


2012 ◽  
Vol 112 (6) ◽  
pp. 063503 ◽  
Author(s):  
K. K. Song ◽  
P. Gargarella ◽  
S. Pauly ◽  
G. Z. Ma ◽  
U. Kühn ◽  
...  

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