State distribution and ambipolar diffusion length inn‐type hydrogenated amorphous silicon

1989 ◽  
Vol 66 (1) ◽  
pp. 215-218 ◽  
Author(s):  
I. Balberg ◽  
S. Z. Weisz
Keyword(s):  
Amorphous Silicon ◽  
Diffusion Length ◽  
Hydrogenated Amorphous Silicon ◽  
Ambipolar Diffusion ◽  
State Distribution ◽  
Hydrogenated Amorphous

Assessment of Intrinsic-Layer Growth Temperature to High-Deposition-Rate a-Si:H n-i-p Solar Cells Deposited by Hot-Wire CVD

1999 ◽  
Vol 557 ◽  
Author(s):  
Qi Wang ◽  
Eugene Iwaniczko ◽  
Yueqin Xu ◽  
Brent P. Nelson ◽  
A. H. Mahan
Keyword(s):  
Solar Cells ◽  
Substrate Temperature ◽  
Amorphous Silicon ◽  
Diffusion Length ◽  
Defect Density ◽  
Hydrogenated Amorphous Silicon ◽  
Ambipolar Diffusion ◽  
Hot Wire ◽  
Top Contact ◽  
Hydrogenated Amorphous

AbstractWe report progress in hydrogenated amorphous silicon n-i-p solar cells with the i-layer grown by the hot-wire chemical vapor deposition technique. Early research showed that we grew device-quality materials with low saturated defect density (2 × 106/cm3), high initial ambipolar diffusion length (~2000 Å) and low hydrogen content (<1%). One of the major barriers to implementing this material into solar cells is the high substrate temperature required (>400°C). We re-assess the effects of low substrate temperature on the property of the films and the performance of the solar cells as an alternative avenue to solving this problem. We find that the material grown at 300°C can have similar values of saturated defect density and ambipolar diffusion length as the one grown greater than 400°C. We also study the effect of i-layer substrate temperature ranging from 280° to 440°C for n-i-p solar cells. We now consistently grow devices with Fill Factor (FF) greater than 0.66, with the best close to 0.70 at lower substrate temperature. A collaboration with United Solar System, in where they grew the p-layer and top contact, produced devices with initial efficiencies as high as 9.8%. We produce n-i-p solar cells with initial efficiencies as high as 8% when we grow all the hydrogenated amorphous silicon and top contact layers. All these i-layers are grown at deposition rates of 16 to 18 Å/sec. We need to further improve our p-layer and transparent conductor layer to equal the collaborative cell efficiency. We also report light-soaking results of these devices.

Deposition of Device Quality Amorphous Silicon by Hot-Wire CVD

1997 ◽  
Vol 467 ◽  
Author(s):  
K. F. Feenstra ◽  
C. H. M. Van Der Werf ◽  
E. C. Molenbroek ◽  
R. E. I. Schropp
Keyword(s):  
Growth Rate ◽  
Electrical Properties ◽  
Amorphous Silicon ◽  
Diffusion Length ◽  
Hydrogenated Amorphous Silicon ◽  
Dark Conductivity ◽  
Hot Wire ◽  
Tungsten Filaments ◽  
Wire Method ◽  
Hydrogenated Amorphous

ABSTRACTIn this paper we present the results of the optimization of hydrogenated amorphous silicon films deposited by the hot-wire method in a larger area system. Using a two-wire design, we succeeded in depositing films that exhibit uniform electrical properties over the whole 4” x 4” Corning 7059 glass substrate. At a substrate temperature of 430 °C. and a pressure of 20 μbar we obtained a growth rate of ∼2 nm/s. The temperature of the tungsten filaments was kept at 1850 °C. The values for the photoconductivity and dark conductivity were 8.9×10−6 S/cm and 1.6×10−10 S/cm respectively, whereas the ambipolar diffusion length, as measured with the Steady-State Photocarrier Grating technique (SSPG), amounted to 145 nm. This value is higher than for our device quality glow-discharge (GD) films, which yield devices with efficiencies higher than 10%. The hydrogen content was 9.5%.We report on the density-of-states (DOS) distribution in the films, which was measured with the techniques of Thermally Stimulated Conductivity (TSC) and Constant Photocurrent Method (CPM). Furthermore, we describe the behavior of the electrical properties on light-induced degradation. Finally, we incorporated these films in solar cells, using conventional GD doped layers. Preliminary SS/n-i-p/ITO devices yielded efficiencies in excess of 3% under 100 mW/cm2 AM 1.5 illumination. Further work concerning the optimization of the interfaces is in progress.

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