The influence of water on the structural and transport properties of model ionic liquids

2010 ◽  
Vol 132 (23) ◽  
pp. 234510 ◽  
Author(s):  
Heidrun V. Spohr ◽  
G. N. Patey
Keyword(s):  
Ionic Liquids ◽  
Transport Properties ◽  
Influence Of Water

The Influence of Water and Metal Salt on the Transport and Structural Properties of 1-Octyl-3-methylimidazolium Chloride

2015 ◽  
Vol 68 (3) ◽  
pp. 420 ◽  
Author(s):  
Nicolas Goujon ◽  
Nolene Byrne ◽  
Tiffany R. Walsh ◽  
Maria Forsyth
Keyword(s):  
Ionic Liquids ◽  
Transport Properties ◽  
Zinc Chloride ◽  
Magnesium Chloride ◽  
Metal Salt ◽  
Metal Salts ◽  
Storage Devices ◽  
Ion Interactions ◽  
Water Structuring ◽  
Influence Of Water

The addition of diluents to ionic liquids (ILs) has recently been shown to enhance the transport properties of ILs. In the context of electrolyte design, this enhancement allows the realisation of IL-based electrolytes for metal–air batteries and other storage devices. It is likely that diluent addition not only impacts the viscosity of the IL, but also the ion–ion interactions and structure. Here, we investigate the nano-structured 1-methyl-3-octylimidazolium chloride (OMImCl) with varying water concentrations in the presence of two metal salts, zinc chloride and magnesium chloride. We find that the choice of metal salt has a significant impact on the structure and transport properties of the system; this is explained by the water structuring and destructing properties of the metal salt.

Influence of Water on Diffusion in Imidazolium-Based Ionic Liquids: A Pulsed Field Gradient NMR study

2009 ◽  
Vol 113 (18) ◽  
pp. 6353-6359 ◽  
Author(s):  
Amrish Menjoge ◽  
JaNeille Dixon ◽  
Joan F. Brennecke ◽  
Edward J. Maginn ◽  
Sergey Vasenkov
Keyword(s):  
Ionic Liquids ◽  
Field Gradient ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Nmr Study ◽  
Influence Of Water

Thermal, Rheological, and Ion-Transport Properties of Phosphonium-Based Ionic Liquids

2011 ◽  
Vol 115 (47) ◽  
pp. 13829-13835 ◽  
Author(s):  
Matthew D. Green ◽  
Christian Schreiner ◽  
Timothy E. Long
Keyword(s):  
Ionic Liquids ◽  
Ion Transport ◽  
Transport Properties

scholarly journals Strange behaviour of transport properties in novel metal thiocyanate based ionic liquids

2021 ◽  
pp. 117164
Author(s):  
Oscar Cabeza ◽  
Luisa Segade ◽  
Montserrat Domínguez-Pérez ◽  
Esther Rilo ◽  
David Ausín ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Transport Properties

Transport properties in a family of dialkylimidazolium ionic liquids

2004 ◽  
Vol 6 (8) ◽  
pp. 1758-1765 ◽  
Author(s):  
Hayley A. Every ◽  
Andrea G. Bishop ◽  
Douglas R. MacFarlane ◽  
Greger Orädd ◽  
Maria Forsyth
Keyword(s):  
Ionic Liquids ◽  
Transport Properties
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