The impact of the Fermi–Dirac distribution on charge injection at metal/organic interfaces

2010 ◽  
Vol 132 (17) ◽  
pp. 174708 ◽  
Author(s):  
Z. B. Wang ◽  
M. G. Helander ◽  
M. T. Greiner ◽  
Z. H. Lu
Keyword(s):  
Charge Injection ◽  
Organic Interfaces ◽  
Metal Organic ◽  
Dirac Distribution ◽  
The Impact

Abnormal charge injection behavior at metal-organic interfaces

2008 ◽  
Vol 78 (19) ◽  
Author(s):  
Z. B. Wang ◽  
M. G. Helander ◽  
S. W. Tsang ◽  
Z. H. Lu
Keyword(s):  
Charge Injection ◽  
Organic Interfaces ◽  
Metal Organic

scholarly journals Unravelling thermal stress due to thermal expansion mismatch in metal–organic frameworks for methane storage

2021 ◽  
Author(s):  
Jelle Wieme ◽  
Veronique Van Speybroeck
Keyword(s):  
Thermal Expansion ◽  
Thermal Stress ◽  
Pressure Coefficient ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Thermal Expansion Mismatch ◽  
Thermal Pressure ◽  
Temperature Changes ◽  
Metal Organic ◽  
The Impact

Thermal stress is present in metal–organic frameworks undergoing temperature changes during adsorption and desorption. We computed the thermal pressure coefficient as a proxy for this phenomenon and discuss the impact of thermal expansion mismatch.

Slope parameters at metal-organic interfaces

2008 ◽  
Vol 93 (9) ◽  
pp. 093502 ◽  
Author(s):  
Y. C. Zhou ◽  
J. X. Tang ◽  
Z. T. Liu ◽  
C. S. Lee ◽  
S. T. Lee
Keyword(s):  
Organic Interfaces ◽  
Metal Organic

The impact of metal ions on photoinduced electron-transfer properties: four photochromic metal–organic frameworks based on a naphthalenediimide chromophore

CrystEngComm ◽  
2018 ◽  
Vol 20 (17) ◽  
pp. 2430-2439 ◽  
Author(s):  
Hui-Ling Xu ◽  
Xiao-Shan Zeng ◽  
Jie Li ◽  
Yu-Ci Xu ◽  
Hai-Jiang Qiu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Metal Ions ◽  
Significant Role ◽  
Photoinduced Electron Transfer ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Electron Transfer Properties ◽  
The Impact ◽  
Transfer Properties

Four photochromic MOFs show that electron-withdrawing capabilities of metal ions play a significant role in tuning the photosensitivity of photochromic MOFs.

scholarly journals Phase-Selective Microwave Assisted Synthesis of Iron(III) Aminoterephthalate MOFs

Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1469 ◽  
Author(s):  
Ana Arenas-Vivo ◽  
David Avila ◽  
Patricia Horcajada
Keyword(s):  
Reaction Medium ◽  
Microwave Assisted Synthesis ◽  
X Ray Diffraction ◽  
Synthetic Strategy ◽  
Transmission Electron ◽  
Metal Organic ◽  
High Space ◽  
Pure Phases ◽  
The Impact ◽  
Reaction Media

Iron(III) aminoterephthalate Metal-Organic Frameworks (Fe-BDC-NH2 MOFs) have been demonstrated to show potential for relevant industrial and societal applications (i.e., catalysis, drug delivery, gas sorption). Nevertheless, further analysis is required in order to achieve their commercial production. In this work, a systematic synthetic strategy has been followed, carrying out microwave (MW) assisted hydro/solvothermal reactions to rapidly evaluate the influence of different reaction parameters (e.g., time, temperature, concentration, reaction media) on the formation of the benchmarked MIL-101-NH2, MIL-88B-NH2, MIL-53-NH2 and MIL-68-NH2 solids. Characterization of the obtained solids by powder X-ray diffraction, dynamic light scattering and transmission electron microscopy allowed us to identify trends to the contribution of the evaluated parameters, such as the relevance of the concentration of precursors and the impact of the reaction medium on phase crystallization. Furthermore, we presented here for the first time the MW assisted synthesis of MIL-53-NH2 in water. In addition, pure MIL-101-NH2 was also produced in water while MIL-88-NH2 was the predominant phase obtained in ethanol. Pure phases were produced with high space-time yields, unveiling the potential of MW synthesis for MOF industrialization.

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