Interfacial electronic structure of copper hexadecafluorophthalocyanine and phthalocyanatotin (IV) dichloride studied by photoemission spectroscopy

2010 ◽  
Vol 96 (17) ◽  
pp. 173303 ◽  
Author(s):  
Haibo Wang ◽  
Zengtao Liu ◽  
Tsz Wai Ng ◽  
Ming Fai Lo ◽  
Chun-Sing Lee ◽  
...  
2008 ◽  
Vol 92 (12) ◽  
pp. 122105 ◽  
Author(s):  
H. Kumigashira ◽  
M. Minohara ◽  
M. Takizawa ◽  
A. Fujimori ◽  
D. Toyota ◽  
...  

Author(s):  
Kaname Kanai ◽  
Takuya Inoue ◽  
Takaya Furuichi ◽  
Kaito Shinoda ◽  
Takashi Iwahashi ◽  
...  

A series of n-cycloparaphenylenes ([n]CPP) were studied by ultraviolet photoemission, inverse photoemission, ultraviolet-visible absorption, and X-ray photoemission spectroscopy to detect their unique electronic structures. [n]CPP has a cyclic structure in...


2003 ◽  
Vol 90 (19) ◽  
Author(s):  
J. Hayoz ◽  
C. Koitzsch ◽  
M. Bovet ◽  
D. Naumović ◽  
L. Schlapbach ◽  
...  

2021 ◽  
Author(s):  
Giorgia Olivieri ◽  
Gregor Kladnik ◽  
Dean Cvetko ◽  
Matthew A. Brown

The electronic structure of hydrated nanoparticles can be unveiled by coupling a liquid microjet with a resonant photoemission spectroscopy.


2021 ◽  
pp. 104692
Author(s):  
Pan Yuan ◽  
Yuquan Liu ◽  
Haipeng Xie ◽  
Junhua Wei ◽  
Yuan Zhao ◽  
...  

Crystals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 547
Author(s):  
Zengguang Tang ◽  
Liujiang Zhang ◽  
Zhenhuang Su ◽  
Zhen Wang ◽  
Li Chen ◽  
...  

In this article, CsPbI2Br perovskite thin films were spin-coated on FTO, on which CuPc was deposited by thermal evaporation. The electronic structure at the CsPbI2Br/CuPc interface was examined during the CuPc deposition by in situ X-ray photoelectron spectroscopy (XPS) and ultraviolet photoelectron spectroscopy (UPS) measurements. No downward band bending was resolved at the CsPbI2Br side, whereas there is ~0.23 eV upward band bending as well as a dipole of ~0.08 eV identified at the molecular side. Although the hole injection barrier as indicated by the energy gap from CsPbI2Br valance band maximum (VBM) to CuPc highest occupied molecular orbital (HOMO) was estimated to be ~0.26 eV, favoring hole extraction from CsPbI2Br to CuPc, the electron blocking barrier of ~0.04 eV as indicated by the offset between CsPbI2Br conduction band minimum (CBM) and CuPc lowest unoccupied molecular orbital (LUMO) is too small to efficiently block electron transfer. Therefore, the present experimental study implies that CuPc may not be a promising hole transport material for high-performance solar cells using CsPbI2Br as active layer.


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