Massive field theory approach for polymer chains in confined geometries

Abstract Building upon the worldline effective field theory (EFT) formalism for spinning bodies developed for the Post-Newtonian regime, we generalize the EFT approach to Post-Minkowskian (PM) dynamics to include rotational degrees of freedom in a manifestly covariant framework. We introduce a systematic procedure to compute the total change in momentum and spin in the gravitational scattering of compact objects. For the special case of spins aligned with the orbital angular momentum, we show how to construct the radial action for elliptic-like orbits using the Boundary-to-Bound correspondence. As a paradigmatic example, we solve the scattering problem to next-to-leading PM order with linear and bilinear spin effects and arbitrary initial conditions, incorporating for the first time finite-size corrections. We obtain the aligned-spin radial action from the resulting scattering data, and derive the periastron advance and binding energy for circular orbits. We also provide the (square of the) center-of-mass momentum to $$ \mathcal{O}\left({G}^2\right) $$ O G 2 , which may be used to reconstruct a Hamiltonian. Our results are in perfect agreement with the existent literature, while at the same time extend the knowledge of the PM dynamics of compact binaries at quadratic order in spins.

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Investigation of Ring and Star Polymers in Confined Geometries: Theory and Simulations

Entropy ◽

10.3390/e23020242 ◽

2021 ◽

Vol 23 (2) ◽

pp. 242

Author(s):

Joanna Halun ◽

Pawel Karbowniczek ◽

Piotr Kuterba ◽

Zoriana Danel

Keyword(s):

Star Polymers ◽

Polymer Chains ◽

The Other ◽

Nano Particles ◽

Dilute Solution ◽

Confined Geometries ◽

Density Profiles ◽

Ideal Ring ◽

Ring Polymer ◽

Monomer Density

The calculations of the dimensionless layer monomer density profiles for a dilute solution of phantom ideal ring polymer chains and star polymers with f=4 arms in a Θ-solvent confined in a slit geometry of two parallel walls with repulsive surfaces and for the mixed case of one repulsive and the other inert surface were performed. Furthermore, taking into account the Derjaguin approximation, the dimensionless layer monomer density profiles for phantom ideal ring polymer chains and star polymers immersed in a solution of big colloidal particles with different adsorbing or repelling properties with respect to polymers were calculated. The density-force relation for the above-mentioned cases was analyzed, and the universal amplitude ratio B was obtained. Taking into account the small sphere expansion allowed obtaining the monomer density profiles for a dilute solution of phantom ideal ring polymers immersed in a solution of small spherical particles, or nano-particles of finite size, which are much smaller than the polymer size and the other characteristic mesoscopic length of the system. We performed molecular dynamics simulations of a dilute solution of linear, ring, and star-shaped polymers with N=300, 300 (360), and 1201 (4 × 300 + 1-star polymer with four arms) beads accordingly. The obtained analytical and numerical results for phantom ring and star polymers are compared with the results for linear polymer chains in confined geometries.

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