A calculation of the thermodynamic first order amorphous semiconductor to metallic liquid transition temperature

1979 ◽  
Author(s):  
B. G. Bagley ◽  
H. S. Chen
Keyword(s):  
Transition Temperature ◽  
Amorphous Semiconductor ◽  
Metallic Liquid ◽  
First Order ◽  
Liquid Transition

Lattice expansion of α-bis-(N-methylsalicylaldiminato)-copper(II)

1981 ◽  
Vol 154 (3-4) ◽  
Author(s):  
W. Adlhart ◽  
V. K. Syal
Keyword(s):  
Phase Transition ◽  
Transition Temperature ◽  
Monoclinic Phase ◽  
Lattice Expansion ◽  
X Rays ◽  
First Order

Abstract.The lattice expansion of α-bis-(N-methylsalicylaldiminato)copper(II) powder was measured by X-rays with the focussing Guinier method from 90 – 320 K. The orthorhombic-monoclinic phase transition is of first order and its transition temperature is 237 ± 2 K.

CRITICAL BEHAVIOR OF THE SPECIFIC HEAT IN THE VICINITY OF THE TRANSITION TEMPERATURE FOR S-TRIAZINE

2009 ◽  
Vol 23 (09) ◽  
pp. 2253-2259 ◽  
Author(s):  
M. KURT ◽  
H. YURTSEVEN
Keyword(s):  
Experimental Data ◽  
Phase Transition ◽  
Transition Temperature ◽  
Critical Exponent ◽  
Specific Heat ◽  
Power Law ◽  
Order Phase Transition ◽  
Critical Behavior ◽  
First Order ◽  
Second Order Phase Transition

The critical behavior of the specific heat is studied in s-triazine ( C 3 N 3 H 3). Using the experimental data for the CP, the temperature dependence of the specific heat is analyzed according to a power-law formula and the values of the critical exponent for CP are extracted in the vicinity of the transition temperature (TC=198.07 K ). It is indicated that s-triazine undergoes a weakly first order (quasi-continuous) or second order phase transition.

FIRST ORDER PHASE TRANSITIONS, WHEN AND FROM WHERE DO THEY EMERGE? —THE CASE OF GELS

1995 ◽  
Vol 09 (07) ◽  
pp. 737-749 ◽  
Author(s):  
KEN SEKIMOTO
Keyword(s):  
Phase Transition ◽  
Transition Temperature ◽  
Transition Point ◽  
The Other ◽  
Basic Fact ◽  
Theoretical Understanding ◽  
First Order ◽  
First Order Phase Transition ◽  
The One ◽  
First Order Phase

We briefly review the recent theoretical understanding of the first order phase transition undergone by gels with an emphasis on physical concepts, deliberately excluding details of modeling and analytic methods. The density of a gel changes discontinuously at the transition point. A variety of features of the transition result from the basic fact that the inhomogeneity of the density of the gel inevitably causes shear deformation. This deformation, on the one hand, reflects the geometry of the sample and, on the other hand, may alter the transition temperature.

Size-dependent ultrahigh electrocaloric effect near pseudo-first-order phase transition temperature in barium titanate nanoparticles

RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37476-37484 ◽  
Author(s):  
Hong-Hui Wu ◽  
Jiaming Zhu ◽  
Tong-Yi Zhang
Keyword(s):  
Phase Transition ◽  
Transition Temperature ◽  
Order Phase Transition ◽  
Electrocaloric Effect ◽  
First Order ◽  
Size Dependent ◽  
First Order Phase Transition ◽  
Pseudo First Order ◽  
Barium Titanate Nanoparticles ◽  
First Order Phase

The proposed Pseudo-First-Order Phase Transition in a ferroelectric nanoparticle occurs at a temperature lower than its paraelectric/ferroelectric transition Curie temperature and is associated with an ultrahigh electrocaloric effect.

X-ray study of the twinning and phase transformation of phosphocristobalite (AlPO4)

1977 ◽  
Vol 55 (7-8) ◽  
pp. 677-683 ◽  
Author(s):  
H. N. Ng ◽  
C. Calvo
Keyword(s):  
Phase Transformation ◽  
Transition Temperature ◽  
Short Range ◽  
X Ray ◽  
First Order ◽  
Β Phase ◽  
Α Phase ◽  
Short Range Correlations

Crystals of the cristobalite polymorph of AlPO4 (phosphocristobalite) up to 3 mm in breadth were grown from a V2O5 flux. In the α phase (C2221), the presence of twin domains prevents an accurate resolution of the structure as a function of temperature. The six twin components of this phase readily lead to a disordered β phase [Formula: see text] with short range correlations as suggested previously. The α–β transformation is first order with a substantial hysteresis in the transition temperature.

Structure Transition and Electrocaloric Effect of Pb(Zr1-xTix)O3 at High Field

2013 ◽  
Vol 432 ◽  
pp. 3-6
Author(s):  
Wen Jiang Feng ◽  
Zhi Guo Zhang ◽  
Chuang Wu ◽  
Hao Chen
Keyword(s):  
High Temperature ◽  
Transition Temperature ◽  
Electric Field ◽  
High Field ◽  
Structural Transition ◽  
Strong Electric Field ◽  
Zero Field ◽  
Electrocaloric Effect ◽  
Structure Transition ◽  
First Order

We investigated the structure transition and the electrocaloric effect in PbZr1-xTixO3 (PZT) with x=0.7, 0.8 and 0.9. The results show that 50 MV/m can make the structural transition be a continuous one. When x=0.7, 0.8 and 0.9 at the zero field, the first order structural transition occurs at T0=685, 687, and 698 K, respectively. Upon a strong electric field, the first order structural transition comes to the second one, which leads to lower the change of specific heat. The structural transition temperature is shifted at high temperature with increasing electric field. The maximum electrocaloric effect is present occurs at about 200 K above the corresponding Curie temperature. With increasing composition of Ti, the electrocaloric effect is enlarged, together with increasing structure transition temperatures.

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