scholarly journals Structural analysis of ultrafast extended x-ray absorption fine structure with subpicometer spatial resolution: Application to spin crossover complexes

2009 ◽  
Vol 130 (12) ◽  
pp. 124520 ◽  
Author(s):  
W. Gawelda ◽  
V.-T. Pham ◽  
R. M. van der Veen ◽  
D. Grolimund ◽  
R. Abela ◽  
...  
2016 ◽  
Vol 83 (2) ◽  
pp. 298-301
Author(s):  
N. Monarumit ◽  
N. Noirawee ◽  
A. Phlayrahan ◽  
K. Promdee ◽  
K. Won-in ◽  
...  

2009 ◽  
Vol 113 (7) ◽  
pp. 2066-2070 ◽  
Author(s):  
Yang Zou ◽  
Hongjie Xu ◽  
Guozhong Wu ◽  
Zheng Jiang ◽  
Shimou Chen ◽  
...  

2016 ◽  
Vol 6 (18) ◽  
pp. 6942-6952 ◽  
Author(s):  
S. Peredkov ◽  
S. Peters ◽  
M. Al-Hada ◽  
A. Erko ◽  
M. Neeb ◽  
...  

Structural analysis of deposited nanoclusters using extended X-ray absorption fine structure (EXAFS) spectroscopy.


1994 ◽  
Vol 98 (33) ◽  
pp. 7967-7975 ◽  
Author(s):  
Toshiharu Teranishi ◽  
Masafumi Harada ◽  
Kiyotaka Asakura ◽  
Hiroyuki Asanuma ◽  
Yasukazu Saito ◽  
...  

2012 ◽  
Vol 3 ◽  
pp. 789-797 ◽  
Author(s):  
Carla Bittencourt ◽  
Peter Krüger ◽  
Maureen J Lagos ◽  
Xiaoxing Ke ◽  
Gustaaf Van Tendeloo ◽  
...  

Recent advances in near-edge X-ray-absorption fine-structure spectroscopy coupled with transmission X-ray microscopy (NEXAFS–TXM) allow large-area mapping investigations of individual nano-objects with spectral resolution up to E/ΔE = 104 and spatial resolution approaching 10 nm. While the state-of-the-art spatial resolution of X-ray microscopy is limited by nanostructuring process constrains of the objective zone plate, we show here that it is possible to overcome this through close coupling with high-level theoretical modelling. Taking the example of isolated bundles of hydrothermally prepared sodium titanate nanotubes ((Na,H)TiNTs) we are able to unravel the complex nanoscale structure from the NEXAFS–TXM data using multichannel multiple-scattering calculations, to the extent of being able to associate specific spectral features in the O K-edge and Ti L-edge with oxygen atoms in distinct sites within the lattice. These can even be distinguished from the contribution of different hydroxyl groups to the electronic structure of the (Na,H)TiNTs.


1998 ◽  
Vol 58 (21) ◽  
pp. 14238-14244 ◽  
Author(s):  
T. Yokoyama ◽  
Y. Murakami ◽  
M. Kiguchi ◽  
T. Komatsu ◽  
N. Kojima

2014 ◽  
Vol 21 (4) ◽  
pp. 756-761 ◽  
Author(s):  
Yonghua Du ◽  
Jia-ou Wang ◽  
Longhua Jiang ◽  
Lucas Santiago Borgna ◽  
Yanfei Wang ◽  
...  

Obtaining sub-10 pm spatial resolution by extended X-ray absorption fine structure (EXAFS) spectroscopy is required in many important fields of research, such as lattice distortion studies in colossal magnetic resistance materials, high-temperature superconductivity materialsetc.However, based on the existing EXAFS data analysis methods, EXAFS has a spatial resolution limit of π/2Δkwhich is larger than 0.1 Å. In this paper a new data analysis method which can easily achieve sub-10 pm resolution is introduced. Theoretically, the resolution limit of the method is three times better than that normally available. The method is examined by numerical simulation and experimental data. As a demonstration, the LaFe1–xCrxO3system (x= 0, 1/3, 2/3) is studied and the structural information of FeO6octahedral distortion as a function of Cr doping is resolved directly from EXAFS, where a resolution better than 0.074 Å is achieved.


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