Temperature and Concentration Dependence of the High Temperature Magnetic Susceptibility of Dilute Alloys

1972 ◽  
Author(s):  
L. Shen ◽  
M. W. Klein
1979 ◽  
Vol 40 (C5) ◽  
pp. C5-17-C5-18
Author(s):  
M. de Jong ◽  
P. Touborg ◽  
J. Bijvoet

1993 ◽  
Vol 07 (01n03) ◽  
pp. 867-870 ◽  
Author(s):  
H. SHIRAISHI ◽  
T. HORI ◽  
Y. YAMAGUCHI ◽  
S. FUNAHASHI ◽  
K. KANEMATSU

The magnetic susceptibility measurements have been made on antiferromagnetic compounds Mn1–xFexSn2 and the magnetic phase diagram was illustrated. The high temperature magnetic phases I and III, major phases, were analyzed on the basis of molecular field theory and explained the change of magnetic structure I⇌III occured at x≈0.8.


2003 ◽  
Vol 17 (24) ◽  
pp. 1271-1275 ◽  
Author(s):  
I. ARDELEAN ◽  
C. ANDRONACHE ◽  
P. PǍŞCUŢǍ

The temperature dependence of the magnetic susceptibility of x Fe 2 O 3·(100-x)-[ P 2 O 5· CaO ] glasses with 0<x≤50 mol % have been investigated. These data revealed that the valence states and the distribution of iron ions in the glass matrix depend on the Fe 2 O 3 content. For the glasses with x≤1 mol % only Fe 3+ ions are evidenced. In the case of the glasses with 3≤x≤35 mol % both Fe 3+ and Fe 2 ions co-exist in the P 2 O 5· CaO glass matrix, the Fe 2+ ion content is higher than that of the Fe 3+ ions for glasses with x≥10 mol %. For the glasses with x>35 mol %, the evaluated values of the μ eff indicate either the presence of Fe + ions or the coordination influence on the magnetic moment of iron ions, but the presence of small quantities of the antiferromagnetic or ferrimagnetic interactions between iron ions in studied temperature range cannot be excluded. The high temperature susceptibility results indicate that the iron ions are isolated or participate in dipole-dipole interactions for glasses with x≤35 mol % and are antiferromagnetically coupled for higher contents of Fe 2 O 3.


1997 ◽  
Vol 102 (8) ◽  
pp. 583-588 ◽  
Author(s):  
B. BabićStojić ◽  
Z. Šoškić ◽  
M. Stojić ◽  
A. Szytula ◽  
Z. Tomkowicz

2013 ◽  
Vol 9 (1) ◽  
pp. 433-446 ◽  
Author(s):  
P. S. Minyuk ◽  
T. V. Subbotnikova ◽  
L. L. Brown ◽  
K. J. Murdock

Abstract. Vivianite, a hydrated iron phosphate, is abundant in sediments of Lake El'gygytgyn, located in the Anadyr Mountains of central Chukotka, northeastern Russia (67°30′ N, 172°05′ E). Magnetic measurements, including mass-specific low-field AC magnetic susceptibility, field-dependent magnetic susceptibility, hysteresis parameters, temperature dependence of the induced magnetization, as well as susceptibility in different heating media, provide ample information on vivianite nodules. Electron microprobe analyses, electron microscopy and energy dispersive spectroscopy were used to identify diagnostic minerals. Vivianite nodules are abundant in both sediments of cold (anoxic) and warm (oxic) stages. Magnetic susceptibility of the nodules varies from 0.78 × 10−6 m3 kg−1 to 1.72 × 10−6 m3 kg−1 (average = 1.05 × 10−6 m3 kg−1) and is higher than the susceptibility of sediments from the cold intervals. Magnetic properties of vivianite are due to the respective product of oxidation as well as sediment and mineral inclusions. Three types of curves for high-temperature dependent susceptibility of vivianite indicate different degrees of oxidation and inclusions in the nodules. Vivianite acts as a reductant and reduces hematite to magnetite and masks the goethite–hematite transition during heating. Heating vivianite and sulfur mixtures stimulates the formation of monoclinic pyrrhotite. An additive of arsenic inhibits the formation of magnetite prior to its Curie temperature. Heating selective vivianite and pyrite mixtures leads to formation of several different minerals – magnetite, monoclinic pyrrhotite, and hexagonal pyrrhotite, and makes it difficult to interpret the thermomagnetic curves.


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