Experimental investigation of the Jahn-Teller effect in the ground and excited electronic states of the tropyl radical. Part II. Vibrational analysis of the ÃE3″2-X̃E2″2 electronic transition

2008 ◽  
Vol 128 (8) ◽  
pp. 084311 ◽  
Author(s):  
Ilias Sioutis ◽  
Vadim L. Stakhursky ◽  
György Tarczay ◽  
Terry A. Miller
1992 ◽  
Vol 291 ◽  
Author(s):  
Michael D. Kaplan

ABSTRACTA microscopic mechanism for the structural phase transition from the orthorhombic mediate temperature (OMT) phase into the low temperature tetragonal (LTT) one is suggested on the basis of the cooperative pseudo Jahn-Teller effect. The local distortions mixing the ground and the first excited electronic states are ordered antiferrodistortively and are connected in part, with the oxygen octahedra rotations around the [100] axis. The results are in agreement, with the neutron scattering experiments data.


1996 ◽  
pp. 231-240
Author(s):  
Mitsunobu NAKAYAMA ◽  
Hiroyuki SHIMIZU ◽  
Sadachika AKIYAMA ◽  
Yoshiyuki KOMURA ◽  
Keizo SUZUKI ◽  
...  

2015 ◽  
Vol 17 (21) ◽  
pp. 14145-14158 ◽  
Author(s):  
Ashim Kumar Saha ◽  
Gautam Sarma ◽  
Chung-Hsin Yang ◽  
Sebastiaan Y. T. van de Meerakker ◽  
David H. Parker ◽  
...  

A simple linear and quadratic force field model for the lifting of the degeneracy on asymmetric isotopic substitution in degenerate electronic states subject to a weak Jahn–Teller effect.


1973 ◽  
Vol 8 (6) ◽  
pp. 2639-2648 ◽  
Author(s):  
B. Lüthi ◽  
M. E. Mullen ◽  
K. Andres ◽  
E. Bucher ◽  
J. P. Maita

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