Experiments Probe the Wavefunction of Electron Pairs in High‐Tc Superconductors

Physics Today ◽  
1996 ◽  
Vol 49 (1) ◽  
pp. 19-22 ◽  
Author(s):  
Barbara Goss Levi
1987 ◽  
Vol 01 (03n04) ◽  
pp. 1049-1055 ◽  
Author(s):  
W.Y. Liang

A simple model is proposed as a possible mechanism for high T c superconductivity in certain copper oxides based on correlated valence fluctuation. Electron pairs are formed by Coulomb attraction between electrons in mainly Cu2+ ( d 9 configuration) pyramidal planes mediated by Cu 3+ ( d 8 configuration) ions in the CuO 4 chain-like plane in YBa2Cu3O7−x . These electron pairs have high binding energies necessary for high Tc , and the model is capable of explaining a number of other observed properties.


1987 ◽  
Vol 99 ◽  
Author(s):  
R. A. Barrio ◽  
C. Wang ◽  
J. Tagüeña-Martinez ◽  
D. Rios-Jara ◽  
T. Akachi ◽  
...  

ABSTRACTBased on very recent experimental evidence about magnetic transitions in high-Tc superconductors the role of superconductivity and magnetism is analyzed. A model of interacting electrons in a one-dimensional system is constructed, taking into account that antiferromagnetic interactions in the underlying lattice are present. The origin of this antiferromagnetism could be due to local Y d-electrons or rare earth f-electrons, related to the structure. Self-consistent calculations in this model show the possibility of a new state, with a gap, in which there are electron pairs. The characteristics of this new state are discussed in relation to superconductivity. The results of this model suggest that an extension of it could be applied to the new superconducting ceramics.


Author(s):  
John Silcox

Determination of the microstructure and microchemistry of small features often provides the insight needed for the understanding of processes in real materials. In many cases, it is not adequate to use microscopy alone. Microdiffraction and microspectroscopic information such as EELS, X-ray microprobe analysis and Auger spectroscopy can all contribute vital parts of the picture. For a number of reasons, dedicated STEM offers considerable promise as a quantitative instrument. In this paper, we review progress towards effective quantitative use of STEM with illustrations drawn from studies of high Tc superconductors, compound semiconductors and metallization of H-terminated silicon.Intrinsically, STEM is a quantitative instrument. Images are acquired directly by detectors in serial mode which is particularly convenient for digital image acquisition, control and display. The VG HB501A at Cornell has been installed in a particularly stable electromagnetic, vibration and acoustic environment. Care has been paid to achieving UHV conditions (i.e., 10-10 Torr). Finally, it has been interfaced with a VAX 3200 work station by Kirkland. This permits, for example, the acquisition of bright field (or energy loss) images and dark field images simultaneously as quantitative arrays in perfect registration.


Author(s):  
Maryvonne Hervieu

Four years after the discovery of superconductivity at high temperature in the Ba-La-Cu-O system, more than thirty new compounds have been synthesized, which can be classified in six series of copper oxides: La2CuO4 - type oxides, bismuth cuprates, YBa2Cu3O7 family, thallium cuprates, lead cuprates and Nd2CuO4 - type oxides. Despite their quite different specific natures, close relationships allow their structures to be simply described through a single mechanism. The fifth first families can indeed be described as intergrowths of multiple oxygen deficient perovskite slabs with multiple rock salt-type slabs, according to the representation [ACuO3-x]m [AO]n.The n and m values are integer in the parent structures, n varying from 0 to 3 and m from 1 to 4; every member of this large family can thus be symbolized by [m,n]. The oxygen deficient character of the perovskite slabs involves the existence or the co-existence of several types of copper environment: octahedral, pyramidal and square planar.Both mechanisms, oxygen deficiency and intergrowth, are well known to give rise easily to nonstoichiometry phenomena. Numerous and various phenomena have actually been characterized in these cuprates, strongly depending on the thermal history of the samples.


PIERS Online ◽  
2005 ◽  
Vol 1 (1) ◽  
pp. 110-114
Author(s):  
Tamio Endo ◽  
Hong Zhu ◽  
Takahisa Sakurada ◽  
Ajay K. Sarkar ◽  
Masanori Okada ◽  
...  

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