Comparative study of temperature dependent orientational relaxation in a model thermotropic liquid crystal and in a model supercooled liquid

2007 ◽  
Vol 126 (20) ◽  
pp. 204906 ◽  
Author(s):  
Dwaipayan Chakrabarti ◽  
Biman Bagchi
Keyword(s):  
Liquid Crystal ◽  
Comparative Study ◽  
Supercooled Liquid ◽  
Temperature Dependent ◽  
Orientational Relaxation ◽  
Thermotropic Liquid Crystal

Reversible microscale assembly of nanoparticles driven by the phase transition of a thermotropic liquid crystal

2017 ◽  
Author(s):  
Niamh Mac Fhionnlaoich ◽  
Stephen Schrettl ◽  
Nicholas B. Tito ◽  
Ye Yang ◽  
Malavika Nair ◽  
...  
Keyword(s):  
Phase Transition ◽  
Liquid Crystal ◽  
Self Assembly ◽  
Nematic Phase ◽  
Hierarchical Control ◽  
Building Blocks ◽  
Model System ◽  
Microscopic Level ◽  
Reversible Process ◽  
Thermotropic Liquid Crystal

The arrangement of nanoscale building blocks into patterns with microscale periodicity is challenging to achieve via self-assembly processes. Here, we report on the phase transition-driven collective assembly of gold nanoparticles in a thermotropic liquid crystal. A temperature-induced transition from the isotropic to the nematic phase leads to the assembly of individual nanometre-sized particles into arrays of micrometre-sized aggregates, whose size and characteristic spacing can be tuned by varying the cooling rate. This fully reversible process offers hierarchical control over structural order on the molecular, nanoscopic, and microscopic level and is an interesting model system for the programmable patterning of nanocomposites with access to micrometre-sized periodicities.

scholarly journals Temperature Characterization of Liquid Crystal Dielectric Image Line Phase Shifter for Millimeter-Wave Applications

Crystals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 63
Author(s):  
Henning Tesmer ◽  
Rani Razzouk ◽  
Ersin Polat ◽  
Dongwei Wang ◽  
Rolf Jakoby ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Millimeter Wave ◽  
Insertion Loss ◽  
Phase Shifter ◽  
Ground Plane ◽  
Temperature Dependent ◽  
Differential Phase ◽  
Dependent Behavior ◽  
The Impact ◽  
Temperature Dependent Behavior

In this paper we investigate the temperature dependent behavior of a liquid crystal (LC) loaded tunable dielectric image guide (DIG) phase shifter at millimeter-wave frequencies from 80 GHz to 110 GHz for future high data rate communications. The adhesive, necessary for precise fabrication, is analyzed before temperature dependent behavior of the component is shown, using the nematic LC-mixture GT7-29001. The temperature characterization is conducted by changing the temperature of the LC DIG’s ground plane between −10∘C and 80 ∘C. The orientation of the LC molecules, and therefore the effective macroscopic relative permittivity of the DIG, is changed by inserting the temperature setup in a fixture with rotatable magnets. Temperature independent matching can be observed, while the insertion loss gradually increases with temperature for both highest and lowest permittivity of the LC. At 80 ∘C the insertion loss is up to 1.3dB higher and at −10∘C it is 0.6dB lower than the insertion loss present at 20 ∘C. In addition, the achievable differential phase is reduced with increasing temperature. The impact of molecule alignment to this reduction is shown for the phase shifter and an estimated 85% of the anisotropy is still usable with an LC DIG phase shifter when increasing the temperature from 20 ∘C to 80 ∘C. Higher reduction of differential phase is present at higher frequencies as the electrical length of the phase shifter increases. A maximum difference in differential phase of 72∘ is present at 110 GHz, when increasing the temperature from 20 ∘C to 80 ∘C. Nevertheless, a well predictable, quasi-linear behavior can be observed at the covered temperature range, highlighting the potential of LC-based dielectric components at millimeter wave frequencies.

Inhomogeneous relaxation dynamics and phase behaviour of a liquid crystal confined in a nanoporous solid

Soft Matter ◽  
2015 ◽  
Vol 11 (16) ◽  
pp. 3176-3187 ◽  
Author(s):  
Sylwia Całus ◽  
Andriy V. Kityk ◽  
Manfred Eich ◽  
Patrick Huber
Keyword(s):  
Liquid Crystal ◽  
Dielectric Spectroscopy ◽  
Phase Behaviour ◽  
Relaxation Dynamics ◽  
Thermotropic Liquid Crystal ◽  
Structure And Dynamics

Dielectric spectroscopy reveals a radial partitioning in the structure and dynamics of a thermotropic liquid crystal confined in silica nanochannels.

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