Effect of interfacial free energy on hydriding reaction of Mg–Ni thin films

2007 ◽  
Vol 90 (2) ◽  
pp. 021917 ◽  
Author(s):  
L. Z. Ouyang ◽  
S. Y. Ye ◽  
H. W. Dong ◽  
M. Zhu
Keyword(s):  
Thin Films ◽  
Free Energy ◽  
Interfacial Free Energy ◽  
Hydriding Reaction

Determining Interfacial Free Energies from Creep Experiments on Silver-Iron Multilayers

1994 ◽  
Vol 356 ◽  
Author(s):  
D. Josell ◽  
Z.L. Wang
Keyword(s):  
Thin Films ◽  
Free Energy ◽  
Boundary Diffusion ◽  
Interfacial Free Energy ◽  
Multilayer Thin Films ◽  
Free Energies ◽  
Diffusion Controlled ◽  
Interfacial Free Energies ◽  
Over Time ◽  
Microstructural Data

AbstractExperiments were conducted on multilayer thin films to determine the free energies associated with silver/iron interfaces. Creep studies determined the loads for which the multilayers neither shrank nor stretched over time. Microstructural data was used with the zero creep loads in a model for grain boundary diffusion controlled creep in multilayers to determine the interfacial free energy.

Interfacial Free Energy Driven Nanophase Separation in Poly(3-hexylthiophene)/[6,6]-Phenyl-C61-butyric Acid Methyl Ester Thin Films

Langmuir ◽  
2012 ◽  
Vol 28 (11) ◽  
pp. 5257-5266 ◽  
Author(s):  
Giovanni Li Destri ◽  
Thomas F. Keller ◽  
Marinella Catellani ◽  
Francesco Punzo ◽  
Klaus D. Jandt ◽  
...  
Keyword(s):  
Thin Films ◽  
Free Energy ◽  
Methyl Ester ◽  
Butyric Acid ◽  
Acid Methyl Ester ◽  
Interfacial Free Energy ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester ◽  
Nanophase Separation

Zero Creep Measurements of the Interfacial Free Energy of Ag/Ni Multilayers

1991 ◽  
Vol 239 ◽  
Author(s):  
D. Josell ◽  
F. Spaepen
Keyword(s):  
Thin Films ◽  
Free Energy ◽  
Grain Boundary ◽  
Interfacial Free Energy ◽  
Specific Model ◽  
Diffusional Creep ◽  
Multilayer Thin Films ◽  
Creep Tests ◽  
Creep Measurements ◽  
Microstructural Data

ABSTRACTThe free energy γAgNi associated with an interface between layers of silver and nickel has been experimentally determined. Creep tests were conducted on multilayer thin films to determine the load at which the length of the film neither shrank nor stretched. The interfacial free energy was obtained from this zero creep load and microstructural data using a specific model for the grain boundary diffusional creep in multilayers.

scholarly journals Curcuminoid-Tailored Interfacial Free Energy of Hydrophobic Fibers for Enhanced Biological Properties

2021 ◽  
Author(s):  
Wevernilson F. de Deus ◽  
Bruna M. de França ◽  
Josué Sebastian B. Forero ◽  
Alessandro E. C. Granato ◽  
Henning Ulrich ◽  
...  
Keyword(s):  
Free Energy ◽  
Interfacial Free Energy ◽  
Biological Properties

Modeling the Diffusion-Controlled Growth of Needle and Plate-Shaped Precipitates

2002 ◽  
Vol 731 ◽  
Author(s):  
Z. Guo ◽  
W. Sha
Keyword(s):  
Free Energy ◽  
Transformation Strain ◽  
Interfacial Free Energy ◽  
Growth Theory ◽  
Controlled Growth ◽  
Precipitate Morphology ◽  
Interface Kinetics ◽  
Diffusion Controlled ◽  
Precipitate Growth ◽  
Strain Stress

AbstractVarious theories have been developed to describe the diffusion-controlled growth of precipitates with shapes approximating needles or plates. The most comprehensive one is due to Ivantsov, Horvay and Cahn, and Trivedi (HIT theory), where all the factors that may influence the precipitate growth, i.e. diffusion, interface kinetics and capillarity, are accounted for within one equation. However, HIT theory was developed based on assumptions that transformation strain/stress and interfacial free energy are isotropic, which are not true in most of the real systems. An improved growth theory of precipitates of needle and plate shapes was developed in the present study. A new concept, the compression ratio, was introduced to account for influences from the anisotropy of transformation strain/stress and interfacial free energy on the precipitate morphology. Experimental evidence supports such compression effect. Precipitate growth kinetics were quantified using this concept. The improved HIT theory (IHIT theory) was then applied to study the growth of Widmanstatten austenite in ferrite in Fe-C-Mn steels. The calculated results agree well with the experimental observations.

Breakthrough of Sublimation Drying by Liquid Phase Deposition

2021 ◽  
Vol 314 ◽  
pp. 172-177
Author(s):  
Yuta Sasaki ◽  
Yousuke Hanawa ◽  
Masayuki Otsuji ◽  
Naozumi Fujiwara ◽  
Masahiko Kato ◽  
...  
Keyword(s):  
Free Energy ◽  
Liquid Phase ◽  
Film Thickness ◽  
Process Parameters ◽  
Interfacial Free Energy ◽  
The Other ◽  
Liquid Phase Deposition ◽  
Drying Method ◽  
Substrate Side ◽  
Drying Technology

Damage-free drying becomes increasingly difficult with the scaling of semiconductor devices. In this work, we studied a new sublimation drying technology for 3nm node and beyond. In order to investigate the collapse factor by conventional sublimation drying, we observed the pattern with cryo-SEM and revealed that the collapse occurred when the liquid film on the substrate solidified. Based on this result, we considered that it was important to deposit a solidified film uniformly from the substrate side to suppress collapse. Two key process parameters were evaluated to achieve the uniform formation of the solidified film. One is interfacial free energy and the other is film thickness of solution just before solidification. By optimizing two key parameters, it was successfully demonstrated to suppress pattern collapse of challenging devices. In this paper, we report on a new drying method: sublimation drying by LPD (Liquid-phase deposition).

ADSORPTION OF BENZENE AND ETHANOL UP TO HIGH RELATIVE PRESSURES ON FINELY DIVIDED SODIUM CHLORIDE: PART I. PARTICLE SIZE EFFECTS AND THE ADSORPTION OF BENZENE: PART II. THE LOWERING OF SURFACE FREE ENERGY BY ETHANOL

1961 ◽  
Vol 39 (6) ◽  
pp. 1360-1371 ◽  
Author(s):  
R. R. Weiler ◽  
J. Beeckmans ◽  
R. McIntosh
Keyword(s):  
Free Energy ◽  
Sodium Chloride ◽  
Surface Free Energy ◽  
Convex Surface ◽  
Plane Surface ◽  
Saturated Vapor ◽  
Thick Layer ◽  
Interfacial Free Energy ◽  
Relative Pressure ◽  
Adsorption Data

Adsorption of benzene has been studied using four samples of fine sodium chloride. The range of relative pressures employed extended to 0.99. The data were employed to show that a correction to the relative pressure should be applied because of the curvature of the surface. The correction was made in the form of a reduction of the apparent relative pressure by application of the Kelvin equation, since the relative pressure over a convex surface would be less than over a plane surface. The adsorption data at high relative pressures for several samples of salt could then be represented by a common curve. It was further concluded that the thick-layer theory of adsorption due to Frenkel, Halsey, and Hill was applicable to adsorption on salt. Adsorption data for ethanol were then obtained and the reduction of surface free energy of the salt by the saturated vapor was evaluated. This figure was then combined with van Zeggeren's and Benson's value of the solid–liquid interfacial free energy for salt and ethanol to provide a provisional value of the surface free energy of sodium chloride of 227 ergs cm−2.

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