Epitaxial growth and B-site cation ordering in layered double perovskite La2CuSnO6 thin films

2006 ◽  
Vol 89 (21) ◽  
pp. 211913 ◽  
Author(s):  
A. Masuno ◽  
M. Haruta ◽  
M. Azuma ◽  
H. Kurata ◽  
S. Isoda ◽  
...  
2007 ◽  
Vol 22 (8) ◽  
pp. 2102-2110 ◽  
Author(s):  
Riad Nechache ◽  
Louis-Philippe Carignan ◽  
Lina Gunawan ◽  
Catalin Harnagea ◽  
Gianluigi A. Botton ◽  
...  

Epitaxial thin films of Bi2FeCrO6 (BFCO) have been synthesized by pulsed laser deposition on SrRuO3 on (100)- and (111)-oriented SrTiO3 substrates. Detailed x-ray diffraction and cross-section transmission electron microscopy analysis revealed a double perovskite crystal structure of the BFCO epitaxial films very similar to that of BiFeO3 along with a particularly noteworthy Fe3+/Cr3+ cation ordering along the [111] direction. The films contain no detectable magnetic iron oxide impurities and have the correct cationic average stoichiometry throughout their thickness. They however exhibit a slight modulation in the Fe and Cr compositions forming complementary stripe patterns, suggesting minor local excess or depletion of Fe and Cr. The epitaxial BFCO films exhibit good ferroelectric and piezoelectric properties, in addition to magnetic properties at room temperature, as well as an unexpected crystallographic orientation dependence of their room-temperature magnetic properties. Our results qualitatively confirm the predictions made using the ab initio calculations: the double perovskite structure of BFCO films exhibit a Fe3+/Cr3+ cation ordering and good multiferroic properties, along with the unpredicted existence of magnetic ordering at room temperature.


1999 ◽  
Vol 606 ◽  
Author(s):  
Keishi Nishio ◽  
Jirawat Thongrueng ◽  
Yuichi Watanabe ◽  
Toshio Tsuchiya

AbstructWe succeeded in the preparation of strontium-barium niobate (Sr0.3Ba0.7Nb2O6 : SBN30)that have a tetragonal tungsten bronze type structure thin films on SrTiO3 (100), STO, or La doped SrTiO3 (100), LSTO, single crystal substrates by a spin coating process. LSTO substrate can be used for electrode. A homogeneous coating solution was prepared with Sr and Ba acetates and Nb(OEt)5 as raw materials, and acetic acid and diethylene glycol monomethyl ether as solvents. The coating thin films were sintered at temperature from 700 to 1000°C for 10 min in air. It was confirmed that the thin films on STO substrate sintered above 700°C were in the epitaxial growth because the 16 diffraction spots were observed on the pole figure using (121) reflection. The <130> and <310> direction of the thin film on STO were oriented with the c-axis in parallel to the substrate surface. However, the diffraction spots of thin film on LSTO substrate sintered at 700°C were corresponds to the expected pattern for (110).


2021 ◽  
pp. 130119
Author(s):  
Ik-Jae Lee ◽  
Hee Seob Kim ◽  
Young Duck Yun ◽  
Seen-Woong Kang ◽  
Hyo-Yun Kim ◽  
...  

2000 ◽  
Vol 18 (2) ◽  
pp. 536-542 ◽  
Author(s):  
Tomoko Wake ◽  
Koichiro Saiki ◽  
Atsushi Koma

1999 ◽  
Vol 85 (8) ◽  
pp. 4800-4802 ◽  
Author(s):  
J. Fontcuberta ◽  
M. Bibes ◽  
B. Martı́nez ◽  
V. Trtik ◽  
C. Ferrater ◽  
...  
Keyword(s):  

2003 ◽  
Vol 83 (26) ◽  
pp. 5500-5502 ◽  
Author(s):  
J.-R. Duclère ◽  
M. Guilloux-Viry ◽  
V. Bouquet ◽  
A. Perrin ◽  
E. Cattan ◽  
...  

Author(s):  
S. Budak ◽  
C. Muntele ◽  
I. Muntele ◽  
H. Guo ◽  
A. Gupta ◽  
...  
Keyword(s):  

1978 ◽  
Vol 45 ◽  
pp. 393-398 ◽  
Author(s):  
Makoto Ishida ◽  
Shinji Tsuji ◽  
Katsutaka Kimura ◽  
Hiroyuki Matsunami ◽  
Tetsuro Tanaka
Keyword(s):  

1996 ◽  
Vol 54 (24) ◽  
pp. R17351-R17354 ◽  
Author(s):  
R. Di Felice ◽  
J. E. Northrup ◽  
J. Neugebauer
Keyword(s):  

2014 ◽  
Vol 130 ◽  
pp. 127-130 ◽  
Author(s):  
Guang Ji ◽  
Aimin Chang ◽  
Hongyi Li ◽  
Yahong Xie ◽  
Huimin Zhang ◽  
...  

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