Loss of chlorine in mass spectra of DCl picked up by water clusters in a beam

2006 ◽  
Vol 124 (14) ◽  
pp. 146102 ◽  
Author(s):  
Ramiro Moro ◽  
Roman Rabinovitch ◽  
Vitaly V. Kresin
Keyword(s):  
1984 ◽  
Vol 108 (4) ◽  
pp. 401-407 ◽  
Author(s):  
O. Echt ◽  
D. Kreisle ◽  
M. Knapp ◽  
E. Recknagel

1984 ◽  
Vol 88 (17) ◽  
pp. 3903-3904 ◽  
Author(s):  
H. Haberland ◽  
H. Langosch ◽  
H. G. Schindler ◽  
D. R. Worsnop

2012 ◽  
Vol 3 (3-4) ◽  
pp. 267-280 ◽  
Author(s):  
Ricardo Velasquez ◽  
Holly Chu ◽  
Shui Yin Lo
Keyword(s):  

2015 ◽  
Vol 12 (1) ◽  
pp. 3910-3918 ◽  
Author(s):  
Dr Remon M Zaki ◽  
Prof Adel M. Kamal El-Dean ◽  
Dr Nermin A Marzouk ◽  
Prof Jehan A Micky ◽  
Mrs Rasha H Ahmed

 Incorporating selenium metal bonded to the pyridine nucleus was achieved by the reaction of selenium metal with 2-chloropyridine carbonitrile 1 in the presence of sodium borohydride as reducing agent. The resulting non isolated selanyl sodium salt was subjected to react with various α-halogenated carbonyl compounds to afford the selenyl pyridine derivatives 3a-f  which compounds 3a-d underwent Thorpe-Ziegler cyclization to give 1-amino-2-substitutedselenolo[2,3-b]pyridine compounds 4a-d, while the other compounds 3e,f failed to be cyclized. Basic hydrolysis of amino selenolo[2,3-b]pyridine carboxylate 4a followed by decarboxylation furnished the corresponding amino selenolopyridine compound 6 which was used as a versatile precursor for synthesis of other heterocyclic compound 7-16. All the newly synthesized compounds were established by elemental and spectral analysis (IR, 1H NMR) in addition to mass spectra for some of them hoping these compounds afforded high biological activity.


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