Molecular-dynamics study of the density scaling of inert gas condensation

2005 ◽  
Vol 123 (15) ◽  
pp. 154314 ◽  
Author(s):  
P. Krasnochtchekov ◽  
K. Albe ◽  
Y. Ashkenazy ◽  
R. S. Averback
Keyword(s):  
Molecular Dynamics ◽  
Inert Gas ◽  
Gas Condensation ◽  
Inert Gas Condensation

Molecular Dynamics Investigation of Structure Evolution and Thermodynamics of Ni-fe Nanoparticles During Inert Gas Condensation

2021 ◽  
Author(s):  
Bei Li ◽  
Lei Pan ◽  
Changan Liu ◽  
Xu Zhang
Keyword(s):  
Molecular Dynamics ◽  
Solid Phase ◽  
Cluster Formation ◽  
Spherical Shape ◽  
Inert Gas ◽  
Structure Evolution ◽  
Solidification Temperature ◽  
Gas Condensation ◽  
Inert Gas Condensation ◽  
Fe Nanoparticles

Abstract Synthesis of magnetic nanoparticles is relevant to many applications in the fields of catalysis, energy storage and biomedicine, etc. Understanding the growth mechanisms and morphology of nanoparticles during inert gas condensation is crucial to rationally improve the performance of the final nanoparticles. In this work, molecular dynamics simulations are carried out to study the structural and thermodynamic behavior of Ni-Fe nanoparticles from homogenous vapor phase in Ar atmosphere. It is revealed that the final morphology of the resulting nanoparticles presents a spherical shape by cluster coalescence at high temperatures where the small clusters are liquid droplets prior to their collisions. However, probabilistic nucleation and cluster growth indicate that the occurrence of spherical shape is more controlled by the probability limits for different Fe concentrations. Meanwhile, a larger inert gas density induces a more efficient cooling effect leading to a larger probability control of the cluster formation with non-spherical shape by agglomeration. Furthermore, the solidification of the as-formed Ni-Fe clusters is examined by evaluating the evolution of crystalline and amorphous structure. The linear scaling-down dependence of the solidification temperature on the reciprocal of the nanoparticle size clearly signifies a linear size-depression effect for the liquid-to-solid phase change of Ni-Fe nanoparticles. Our findings thus extend the current understanding of inert gas condensation behavior and mechanisms of Ni-Fe nanoparticles from an atomic/molecular perspective.

Highly Size-Controlled Synthesis of Metal Nanoclusters by Inert-Gas Condensation for Nano-Devices

2010 ◽  
Vol 10 (5) ◽  
pp. 3667-3670 ◽  
Author(s):  
Il-Suk Kang ◽  
Hyun-Sang Seo ◽  
Deuk-Han Kim ◽  
Taek-Yeong Lee ◽  
Jun-Mo Yang ◽  
...  
Keyword(s):  
Inert Gas ◽  
Controlled Synthesis ◽  
Metal Nanoclusters ◽  
Gas Condensation ◽  
Inert Gas Condensation ◽  
Size Controlled

Inert gas condensation of Sb, Bi and Pb clusters

1981 ◽  
Vol 106 (1-3) ◽  
pp. A170
Author(s):  
J. Mühlbach ◽  
E. Recknagel ◽  
K. Sattler
Keyword(s):  
Inert Gas ◽  
Gas Condensation ◽  
Inert Gas Condensation

Formation Mechanism of Fe Nanocubes by Magnetron Sputtering Inert Gas Condensation

ACS Nano ◽  
2016 ◽  
Vol 10 (4) ◽  
pp. 4684-4694 ◽  
Author(s):  
Junlei Zhao ◽  
Ekaterina Baibuz ◽  
Jerome Vernieres ◽  
Panagiotis Grammatikopoulos ◽  
Ville Jansson ◽  
...  
Keyword(s):  
Magnetron Sputtering ◽  
Formation Mechanism ◽  
Inert Gas ◽  
Gas Condensation ◽  
Inert Gas Condensation
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