Accidental vibrational degeneracy in vibrational excited states observed with ultrafast two-dimensional IR vibrational echo spectroscopy

2005 ◽  
Vol 123 (16) ◽  
pp. 164301 ◽  
Author(s):  
Junrong Zheng ◽  
Kyungwon Kwak ◽  
Tobias Steinel ◽  
John Asbury ◽  
Xin Chen ◽  
...  
Keyword(s):  
Excited States ◽  
Two Dimensional ◽  
Vibrational Echo

scholarly journals Excited state Rényi entropy and subsystem distance in two-dimensional non-compact bosonic theory. Part I. Single-particle states

2020 ◽  
Vol 2020 (12) ◽  
Author(s):  
Jiaju Zhang ◽  
M.A. Rajabpour
Keyword(s):  
Excited States ◽  
Single Particle ◽  
Renyi Entropy ◽  
Rényi Entropy ◽  
Large Momentum ◽  
Particle State ◽  
Two Dimensional ◽  
Universal Form ◽  
Conformal Field ◽  
Harmonic Chain

Abstract We investigate the Rényi entropy of the excited states produced by the current and its derivatives in the two-dimensional free massless non-compact bosonic theory, which is a two-dimensional conformal field theory. We also study the subsystem Schatten distance between these states. The two-dimensional free massless non-compact bosonic theory is the continuum limit of the finite periodic gapless harmonic chains with the local interactions. We identify the excited states produced by current and its derivatives in the massless bosonic theory as the single-particle excited states in the gapless harmonic chain. We calculate analytically the second Rényi entropy and the second Schatten distance in the massless bosonic theory. We then use the wave functions of the excited states and calculate the second Rényi entropy and the second Schatten distance in the gapless limit of the harmonic chain, which match perfectly with the analytical results in the massless bosonic theory. We verify that in the large momentum limit the single-particle state Rényi entropy takes a universal form. We also show that in the limit of large momenta and large momentum difference the subsystem Schatten distance takes a universal form but it is replaced by a new corrected form when the momentum difference is small. Finally we also comment on the mutual Rényi entropy of two disjoint intervals in the excited states of the two-dimensional free non-compact bosonic theory.

scholarly journals Ultrabroadband two-dimensional electronic spectroscopy reveals energy flow pathways in LHCII across the visible spectrum

2019 ◽  
Vol 205 ◽  
pp. 09034
Author(s):  
Minjung Son ◽  
Alberta Pinnola ◽  
Roberto Bassi ◽  
Gabriela S. Schlau-Cohen
Keyword(s):  
Energy Transfer ◽  
Excited States ◽  
Energy Flow ◽  
Energy Levels ◽  
Electronic Spectroscopy ◽  
Visible Region ◽  
Visible Spectrum ◽  
Energy Relaxation ◽  
Two Dimensional ◽  
Flow Pathways

We utilise ultrabroadband two-dimensional electronic spectroscopy to map out pathways of energy flow in LHCII across the entire visible region. In addition to the well-established, low-lying chlorophyll Qy bands, our results reveal additional pathways of energy relaxation on the higher-lying excited states involving the S2 energy levels of carotenoids, including ultrafast carotenoid-to-chlorophyll energy transfer on 90-150 fs timescales.

Interacting fermions in a two-dimensional trap and fractional exclusion statistics

2000 ◽  
Vol 78 (1) ◽  
pp. 9-19 ◽  
Author(s):  
M K Srivastava ◽  
R K Bhaduri ◽  
J Law ◽  
M.V.N. Murthy
Keyword(s):  
Excited States ◽  
State Energy ◽  
Local Density ◽  
Two Dimensional ◽  
Body System ◽  
Oscillator Potential ◽  
Harmonic Oscillator Potential ◽  
Thomas Fermi ◽  
Hartree Fock ◽  
Number Of Particles

We consider N fermions in a two-dimensional harmonic oscillator potential interacting with a very short-range repulsive pair-wise potential. The ground-state energy of this system is obtained by performing a Thomas-Fermi as well as a self-consistent Hartree-Fock calculation. The two results are shown to agree even for a small number of particles. We next use the finite-temperature Thomas-Fermi method to demonstrate that in the local density approximation, these interacting fermions are equivalent to a system of noninteracting particles obeying the Haldane-Wu fractional exclusion statistics. It is also shown that mapping onto a system of N noninteracting quasiparticles enables us to predict the energies of the ground and excited states of the N-body system. PACS Nos.: 05.30-d, 73.20Dx

Two-Dimensional Time-Frequency Ultrafast Infrared Vibrational Echo Spectroscopy

2001 ◽  
Vol 86 (17) ◽  
pp. 3899-3902 ◽  
Author(s):  
K. A. Merchant ◽  
David E. Thompson ◽  
M. D. Fayer
Keyword(s):  
Two Dimensional ◽  
Time Frequency ◽  
Vibrational Echo ◽  
Ultrafast Infrared

scholarly journals Excited States Calculations of MoS2@ZnO and WS2@ZnO Two-Dimensional Nanocomposites for Water-Splitting Applications

Energies ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 150
Author(s):  
Yin-Pai Lin ◽  
Boris Polyakov ◽  
Edgars Butanovs ◽  
Aleksandr A. Popov ◽  
Maksim Sokolov ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Optical Properties ◽  
Water Splitting ◽  
Excited States ◽  
Density Functional ◽  
Visible Region ◽  
Transition Metal Dichalcogenide ◽  
Two Dimensional ◽  
Functional Theory ◽  
Exchange Correlation

Transition metal dichalcogenide (TMD) MoS2 and WS2 monolayers (MLs) deposited atop of crystalline zinc oxide (ZnO) and graphene-like ZnO (g-ZnO) substrates have been investigated by means of density functional theory (DFT) using PBE and GLLBSC exchange-correlation functionals. In this work, the electronic structure and optical properties of studied hybrid nanomaterials are described in view of the influence of ZnO substrates thickness on the MoS2@ZnO and WS2@ZnO two-dimensional (2D) nanocomposites. The thicker ZnO substrate not only triggers the decrease of the imaginary part of dielectric function relatively to more thinner g-ZnO but also results in the less accumulated charge density in the vicinity of the Mo and W atoms at the conduction band minimum. Based on the results of our calculations, we predict that MoS2 and WS2 monolayers placed at g-ZnO substrate yield essential enhancement of the photoabsorption in the visible region of solar spectra and, thus, can be used as a promising catalyst for photo-driven water splitting applications.

scholarly journals Two-Dimensional Impulsively Stimulated Resonant Raman Spectroscopy of Molecular Excited States

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Giuseppe Fumero ◽  
Christoph Schnedermann ◽  
Giovanni Batignani ◽  
Torsten Wende ◽  
Matz Liebel ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Excited States ◽  
Two Dimensional ◽  
Resonant Raman ◽  
Molecular Excited States
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