Aerosol mass spectrometer for the in situ analysis of chemical vapor synthesis processes in hot wall reactors

2005 ◽  
Vol 76 (9) ◽  
pp. 095104 ◽  
Author(s):  
In-Kyum Lee ◽  
Markus Winterer
Keyword(s):  
Mass Spectrometer ◽  
Chemical Vapor ◽  
In Situ Analysis ◽  
Chemical Vapor Synthesis ◽  
Aerosol Mass Spectrometer ◽  
Aerosol Mass

In-situ Analysis of the Chemical Vapor Synthesis of Nanocrystalline Silicon Carbide by Aerosol Mass Spectrometry

2001 ◽  
Vol 703 ◽  
Author(s):  
In-Kyum Lee ◽  
Markus Winterer ◽  
Horst Hahn ◽  
Christian Janzen ◽  
Dirk Lindackers ◽  
...  
Keyword(s):  
Silicon Carbide ◽  
Mass Spectrometer ◽  
Process Analysis ◽  
Chemical Vapor ◽  
Nanocrystalline Silicon ◽  
In Situ Analysis ◽  
Aerosol Mass ◽  
Silicon Carbide Particles ◽  
Nanocrystalline Silicon Carbide

ABSTRACTAn Aerosol Mass Spectrometer (AMS) is a combination of a Quadrupol- (QMS) and a Particle Mass Spectrometer (PMS) and enables the in-situ analysis of gas phase processes for the generation of nanoparticles. Size distributions of ultrafine silicon carbide particles in the range of 104atomic mass units (amu) to 107amu are measured in the PMS. Simultaneously, molecular species up to 300 amu can be detected in the QMS. Aerosols containing nanocrystalline silicon carbide are produced from tetramethylsilane (TMS) by thermal decomposition. In situ process analysis with the AMS as a function of process parameters was performed to elucidate the formation and growth mechanism of SiC nanoparticles.

scholarly journals In situ measurement of PM1 organic aerosol in Beijing winter using a high-resolution aerosol mass spectrometer

2011 ◽  
Vol 57 (7) ◽  
pp. 819-826 ◽  
Author(s):  
Quan Liu ◽  
Yang Sun ◽  
Bo Hu ◽  
ZiRui Liu ◽  
Shimono Akio ◽  
...  
Keyword(s):  
High Resolution ◽  
Mass Spectrometer ◽  
Organic Aerosol ◽  
In Situ Measurement ◽  
Aerosol Mass Spectrometer ◽  
Aerosol Mass

Analysis of Cigarette Smoke Aerosol by Single Particle Aerosol Mass Spectrometer

2013 ◽  
Vol 40 (6) ◽  
pp. 936-939
Author(s):  
Mei LI ◽  
Jun-Guo DONG ◽  
Zheng-Xu HUANG ◽  
Lei LI ◽  
Wei GAO ◽  
...  
Keyword(s):  
Cigarette Smoke ◽  
Mass Spectrometer ◽  
Single Particle ◽  
Aerosol Mass Spectrometer ◽  
Smoke Aerosol ◽  
Aerosol Mass

scholarly journals Measurements of Aerosols and Trace Gases in Southern Romania

2017 ◽  
Vol 68 (4) ◽  
pp. 873-878
Author(s):  
Alexandru Dandocsi ◽  
Anca Nemuc ◽  
Cristina Marin ◽  
Simona Andrei
Keyword(s):  
Remote Sensing ◽  
Vertical Profiles ◽  
Aerosol Mass Spectrometer ◽  
Boundary Layer Height ◽  
Passive Remote Sensing ◽  
Aerosol Mass ◽  
Scanning Lidar ◽  
532 Nm

An intensive measurement campaign was performed during September 2014 in southern Romania in two different locations: Magurele, Ilfov County and Turceni, Gorj County. This paper presents one case study with analysis of the aerosol properties from in-situ, passive remote sensing and active remote sensing measurements. A Multiwavelength Raman Lidar (RALI) provided one hour averaged vertical profiles of extinction and backscatter from the 532 nm and 1064 nm channels in Magurele. The UV scanning Lidar (MILI) provided one hour averaged backscattered and extinction vertical profiles for Turceni. Planetary Boundary Layer Height (PBLH) was calculated using the altitude of the maximum negative gradient of the range corrected signal. Mass concentrations for different aerosol species (organics, nitrate, sulphate, ammonium and chloride) were obtained from in-situ measurements using Aerosol Mass Spectrometer located in M�gurele and Aerosol Chemical Speciation Monitor (ACSM) located in Turceni.

scholarly journals Secondary organic aerosol formation from reaction of tertiary amines with nitrate radical

2008 ◽  
Vol 8 (4) ◽  
pp. 16585-16608 ◽  
Author(s):  
M. E. Erupe ◽  
D. J. Price ◽  
P. J. Silva ◽  
Q. G. J. Malloy ◽  
L. Qi ◽  
...  
Keyword(s):  
Mass Spectrometer ◽  
Secondary Organic Aerosol ◽  
Organic Aerosol ◽  
Nitrate Radical ◽  
Tertiary Amines ◽  
Aerosol Formation ◽  
Night Time ◽  
Aerosol Mass Spectrometer ◽  
Aerosol Mass ◽  
Secondary Organic Aerosol Formation

Abstract. Secondary organic aerosol formation from the reaction of tertiary amines with nitrate radical was investigated in an indoor environmental chamber. Particle chemistry was monitored using a high resolution aerosol mass spectrometer while gas-phase species were detected using a proton transfer reaction mass spectrometer. Trimethylamine, triethylamine and tributylamine were studied. Results indicate that tributylamine forms the most aerosol mass followed by trimethylamine and triethylamine respectively. Spectra from the aerosol mass spectrometer indicate the formation of complex non-salt aerosol products. We propose a reaction mechanism that proceeds via abstraction of a proton by nitrate radical followed by RO2 chemistry. Rearrangement of the aminyl alkoxy radical through hydrogen shift leads to the formation of hydroxylated amides, which explain most of the higher mass ions in the mass spectra. These experiments show that oxidation of tertiary amines by nitrate radical may be an important night-time source of secondary organic aerosol.

scholarly journals Characterization of the sources and processes of organic and inorganic aerosols in New York City with a high-resolution time-of-flight aerosol mass spectrometer

2010 ◽  
Vol 10 (10) ◽  
pp. 22669-22723 ◽  
Author(s):  
Y.-L. Sun ◽  
Q. Zhang ◽  
J. J. Schwab ◽  
K. L. Demerjian ◽  
W.-N. Chen ◽  
...  
Keyword(s):  
New York ◽  
New York City ◽  
High Resolution ◽  
Mass Spectrometer ◽  
York City ◽  
Time Of Flight ◽  
Resolution Time ◽  
Aerosol Mass Spectrometer ◽  
Spectral Pattern ◽  
Aerosol Mass

Abstract. Submicron aerosol particles (PM1) were measured in-situ using a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) during the summer 2009 Field Intensive Study at Queens College in New York City. Organic aerosol (OA) and sulfate are the two dominant species, accounting for 54% and 24%, respectively, of total PM1 mass on average. The average mass size distribution of OA presents a small mode peaking at ~150 nm (Dva) in addition to an accumulation mode (~550 nm) that is internally mixed with sulfate, nitrate, and ammonium. The diurnal cycles of sulfate and OA both show pronounced peaks between 01:00–02:00 p.m. EST due to photochemical production. The average (±1σ) oxygen-to-carbon (O/C), hydrogen-to-carbon (H/C), and nitrogen-to-carbon (N/C) ratios of OA in NYC are 0.36 (±0.09), 1.49 (±0.08), and 0.012(±0.005), respectively, corresponding to an average organic mass-to-carbon (OM/OC) ratio of 1.62(±0.11). Positive matrix factorization (PMF) of the high resolution mass spectra identified five OA components: a hydrocarbon-like OA (HOA), two types of oxygenated OA (OOA) including a low-volatility OOA (LV-OOA) and a semi-volatile OOA (SV-OOA), a cooking-emission related OA (COA), and a unique nitrogen-enriched OA (NOA). HOA appears to represent primary OA (POA) from urban traffic emissions. It comprises primarily of reduced species (H/C=1.83; O/C=0.06) and shows a mass spectral pattern very similar to those of POA from fossil fuel combustion, and correlates tightly with traffic emission tracers including elemental carbon and NOx. LV-OOA, which is highly oxidized (O/C=0.63) and correlates well with sulfate, appears to be representative for regional, aged secondary OA (SOA). SV-OOA, which is less oxidized (O/C=0.38) and correlates well with non-refractory chloride, likely represents less photo-chemically aged, semi-volatile SOA. COA shows a similar spectral pattern to the reference spectra of POA from cooking emissions and a distinct diurnal pattern peaking around local lunch and dinner times. In addition, NOA is characterized with prominent CxH2x+2N+ peaks likely from amine compounds. Our results indicate that cooking-related activities are a major source of POA in NYC, releasing comparable amounts of POA as traffic emissions. POA=HOA+COA) on average accounts for ~30% of the total OA mass during this study while SOA dominates the OA composition with SV-OOA and LV-OOA on average accounting for 34% and 30%, respectively, of the total OA mass. The chemical evolution of SOA in NYC involves a~continuous oxidation from SV-OOA to LV-OOA, which is further supported by a gradual increase of O/C ratio and a simultaneous decrease of H/C ratio in total OOA. Detailed analysis of NOA (5.8% of OA) presents evidence that nitrogen-containing organic species such as amines might have played an important role in the atmospheric processing of OA in NYC, likely involving acid-base chemistry. Analysis of air mass trajectories and satellite imagery of aerosol optical depth (AOD) indicates that the high potential source regions of secondary sulfate and aged OA are mainly located in regions to the west and southwest of the city.

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