1s22p3 and 1s22s23l, l=s,p,d, excited states of boron isoelectronic series from explicitly correlated wave functions

2005 ◽  
Vol 123 (3) ◽  
pp. 034302 ◽  
Author(s):  
F. J. Gálvez ◽  
E. Buendía ◽  
A. Sarsa
1985 ◽  
Vol 38 (1) ◽  
pp. 11
Author(s):  
PE Schipper ◽  
B Martire

The exciton model developed in an earlier paper is applied quantitatively to a description of the excited states of representative members of the helium isoelectronic series; viz. H-, He, Li+,Be2+ and Ne8+. The energies of the eight lowest excited states are in good agreement with experiment, for a relatively small (1s-4p) hydrogenic basis; the ground state is obtained with slightly less precision. Response properties including oscillator strengths, polarizabilities and dispersion interaction coefficients are also calculated. The method appears to be quantitatively sound, and, above all, leads to particularly simple interpretations of the wave functions and the energies.


2002 ◽  
Vol 117 (13) ◽  
pp. 6071-6082 ◽  
Author(s):  
F. J. Gálvez ◽  
E. Buendı́a ◽  
A. Sarsa

Author(s):  
Lucas Happ ◽  
Matthias Zimmermann ◽  
Maxim A Efremov

Abstract We study a heavy-heavy-light three-body system confined to one space dimension in the regime where an excited state in the heavy-light subsystems becomes weakly bound. The associated two-body system is characterized by (i) the structure of the weakly-bound excited heavy-light state and (ii) the presence of deeply-bound heavy-light states. The consequences of these aspects for the behavior of the three-body system are analyzed. We find a strong indication for universal behavior of both three-body binding energies and wave functions for different weakly-bound excited states in the heavy-light subsystems.


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