Infrared spectra of the water-nitrogen complexes (H2O)2–(N2)n(n=1–4) in argon matrices

2005 ◽  
Vol 122 (19) ◽  
pp. 194506 ◽  
Author(s):  
Shinichi Hirabayashi ◽  
Kayo Ohno ◽  
Hisashi Abe ◽  
Koichi M. T. Yamada
Keyword(s):  
Infrared Spectra ◽  
Argon Matrices

The Photolysis of Matrix Isolated cis-Thionylimide. 1. The Identification and Infrared Spectra of cis-HOSN, HSNO, and SNO

1975 ◽  
Vol 53 (15) ◽  
pp. 2318-2330 ◽  
Author(s):  
Peter O. Tchir ◽  
Richard D. Spratley
Keyword(s):  
Reaction Time ◽  
Infrared Spectra ◽  
Force Fields ◽  
Reaction Scheme ◽  
Isotopic Substitution ◽  
Mercury Lamp ◽  
Reaction Sequence ◽  
Medium Pressure ◽  
Argon Matrices

cis-HNSO has been photolyzed in argon matrices using a medium pressure mercury lamp. Examination of the infrared spectra has revealed the presence of four photolysis products. With the aid of isotopic substitution these species have been identified as cis-HOSN, cis-HSNO, trans-HSNO, and SNO, all previously unknown. Assignments have been made for all four products and force fields calculated for cis-HOSN and trans-HSNO. The following reaction scheme has been postulated for the photolysis induced process: cis-HNSO → cis-HOSN → cis-HSNO + trans-HSNO → SNO. The extent of this reaction sequence has been found to depend on reaction time and photolysis energy.

Photolysis of 2-methylthietane and 2,4-dimethylthietane in argon matrices: Matrix infrared spectra of thioacetaldehyde

1993 ◽  
Vol 5 (3) ◽  
pp. 353-357 ◽  
Author(s):  
E. Suzuki ◽  
O. Watanabe ◽  
A. Happoya ◽  
E. Watari
Keyword(s):  
Infrared Spectra ◽  
Argon Matrices

"Sideways" Bonded Dinitrogen in Matrix Isolated Cobalt Dinitrogen, CoN2

1973 ◽  
Vol 51 (4) ◽  
pp. 637-640 ◽  
Author(s):  
G. A. Ozin ◽  
A. Vander Voet
Keyword(s):  
Transition Metal ◽  
Metal Atom ◽  
Infrared Spectra ◽  
Transition Metal Atom ◽  
Spectroscopic Evidence ◽  
Isotopic Species ◽  
Argon Matrices

Infrared spectra are reported for matrix isolated cobalt dinitrogen isotopic species, Co14N2, Co14N15N and Co15N2, formed in the cocondensation reaction of atomic cobalt with dilute nitrogen–argon matrices at 10°K. The data provide the first unambiguous spectroscopic evidence for a dinitrogen molecule bonded in a "sideways" fashion to a transition metal atom.

Infrared spectra of dimethylaminomethanol in low-temperature argon matrices and conformational analysis by DFT calculation

2000 ◽  
Vol 524 (1-3) ◽  
pp. 251-258 ◽  
Author(s):  
S. Kudoh ◽  
T. Uechi ◽  
M. Takayanagi ◽  
M. Nakata ◽  
N. Tanaka ◽  
...  
Keyword(s):  
Low Temperature ◽  
Conformational Analysis ◽  
Infrared Spectra ◽  
Dft Calculation ◽  
Argon Matrices

Electronic and infrared spectra of C+60 and C−60 in neon and argon matrices

1993 ◽  
Vol 211 (2-3) ◽  
pp. 227-234 ◽  
Author(s):  
Jan Fulara ◽  
Michael Jakobi ◽  
John P. Maier
Keyword(s):  
Infrared Spectra ◽  
Argon Matrices

Infrared spectra of (HCN)n clusters in low-temperature argon matrices

1997 ◽  
Vol 413-414 ◽  
pp. 365-369 ◽  
Author(s):  
Kudoh Satoshi ◽  
Masao Takayanagi ◽  
Munetaka Nakata
Keyword(s):  
Low Temperature ◽  
Infrared Spectra ◽  
Argon Matrices

Infrared spectra of octaethylporphinatocobalt(II) and its dioxygen adduct in argon matrices

1982 ◽  
Vol 61 ◽  
pp. 77-81 ◽  
Author(s):  
Marek W. Urban ◽  
Kazuo Nakamoto ◽  
James Kincaid
Keyword(s):  
Infrared Spectra ◽  
Argon Matrices

Infrared spectra of the GeSi and SnSi molecules in argon matrices

1994 ◽  
Vol 229 (4-5) ◽  
pp. 531-536 ◽  
Author(s):  
S. Li ◽  
R.J. Van Zee ◽  
W. Weltner
Keyword(s):  
Infrared Spectra ◽  
Argon Matrices
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